Regioselective Baeyer-Villiger reaction of polyhydroxycyclohexanone derivatives

Noritaka Chida, Takahiko Tobe, Seiichiro Ogawa

Research output: Contribution to journalArticle

32 Citations (Scopus)

Abstract

The regioselectivities observed in Baeyer-Villiger reaction of polyhydroxycyclohexanone derivatives possessing various substituents at adjacent carbons to the ketone carbonyl are reported. This study suggested that the trend of the migratory aptitude of substituted carbons would be a carbon with benzyloxy > methoxy > ketal oxygen ≫ acyloxy ∼ methyl.

Original languageEnglish
Pages (from-to)7249-7252
Number of pages4
JournalTetrahedron Letters
Volume35
Issue number39
DOIs
Publication statusPublished - 1994 Sep 26

ASJC Scopus subject areas

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

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