Regioselective oxidation of β-hydroxyazo compounds to β-hydroxyazoxy compounds and its application to syntheses of maniwamycins A and B

Masaya Nakata, Soichiro Kawazoe, Tetsuro Tamai, Kuniaki Tatsuta, Hiroyuki Ishiwata, Yoshio Takahashi, Yukihiro Okuno, Takeo Deushi

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21 Citations (Scopus)

Abstract

A new preparation of β-hydroxyazo compounds and regioselectivities on their oxidation to β-hydroxyazoxy compounds have been described. A new synthesis of antifungal antibiotic maniwamycin A and the first synthesis of maniwamycin B by using this methodology have been also described.

Original languageEnglish
Pages (from-to)6095-6098
Number of pages4
JournalTetrahedron Letters
Volume34
Issue number38
DOIs
Publication statusPublished - 1993 Sep 17

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ASJC Scopus subject areas

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

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