Resolution of racemic Sb-chiral stibindoles using an optically active ortho-palladated benzylamine derivative, via their diastereomeric complexes

Jyoji Kurita, Fujiko Usuda, Shuji Yasuike, Takashi Tsuchiya, Yoshisuke Tsuda, Fumiyuki Kiuchi, Shinzo Hosoi

Research output: Contribution to journalArticle

38 Citations (Scopus)

Abstract

Resolution of racemic Sb-chiral (±)-1-phenyl-2-trimethylsilylstibindole 1 has been achieved by the separation of a mixture of the diastereomeric palladium(II) complexes 3A and 3B derived from the reaction of (±)-1 with di-μ-chlorobis{(S)-2-[1-(dimethylamino)ethyl]phenyl-C,N}dipalladium(II) 2, and optically pure 1-phenylstibindoles (-)-4 and (+)-4 have also been obtained from resolved (-)-1 and (+)-1, respectively.

Original languageEnglish
Pages (from-to)191-192
Number of pages2
JournalChemical Communications
Issue number3
Publication statusPublished - 2000 Feb 7
Externally publishedYes

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Palladium
Derivatives
benzylamine

ASJC Scopus subject areas

  • Chemistry(all)

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Resolution of racemic Sb-chiral stibindoles using an optically active ortho-palladated benzylamine derivative, via their diastereomeric complexes. / Kurita, Jyoji; Usuda, Fujiko; Yasuike, Shuji; Tsuchiya, Takashi; Tsuda, Yoshisuke; Kiuchi, Fumiyuki; Hosoi, Shinzo.

In: Chemical Communications, No. 3, 07.02.2000, p. 191-192.

Research output: Contribution to journalArticle

Kurita, Jyoji ; Usuda, Fujiko ; Yasuike, Shuji ; Tsuchiya, Takashi ; Tsuda, Yoshisuke ; Kiuchi, Fumiyuki ; Hosoi, Shinzo. / Resolution of racemic Sb-chiral stibindoles using an optically active ortho-palladated benzylamine derivative, via their diastereomeric complexes. In: Chemical Communications. 2000 ; No. 3. pp. 191-192.
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AU - Tsuchiya, Takashi

AU - Tsuda, Yoshisuke

AU - Kiuchi, Fumiyuki

AU - Hosoi, Shinzo

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