Resolution of racemic Sb-chiral stibindoles using an optically active ortho-palladated benzylamine derivative, via their diastereomeric complexes

Jyoji Kurita, Fujiko Usuda, Shuji Yasuike, Takashi Tsuchiya, Yoshisuke Tsuda, Fumiyuki Kiuchi, Shinzo Hosoi

Research output: Contribution to journalArticle

39 Citations (Scopus)

Abstract

Resolution of racemic Sb-chiral (±)-1-phenyl-2-trimethylsilylstibindole 1 has been achieved by the separation of a mixture of the diastereomeric palladium(II) complexes 3A and 3B derived from the reaction of (±)-1 with di-μ-chlorobis{(S)-2-[1-(dimethylamino)ethyl]phenyl-C,N}dipalladium(II) 2, and optically pure 1-phenylstibindoles (-)-4 and (+)-4 have also been obtained from resolved (-)-1 and (+)-1, respectively.

Original languageEnglish
Pages (from-to)191-192
Number of pages2
JournalChemical Communications
Issue number3
DOIs
Publication statusPublished - 2000 Feb 7
Externally publishedYes

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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