Resolution of racemic Sb-chiral stibindoles using an optically active ortho-palladated benzylamine derivative, via their diastereomeric complexes

Jyoji Kurita; Fujiko Usuda; Shuji Yasuike; Takashi Tsuchiya; Yoshisuke Tsuda; Fumiyuki Kiuchi; Shinzo Hosoi

doi:10.1039/a909200e

Resolution of racemic Sb-chiral stibindoles using an optically active ortho-palladated benzylamine derivative, via their diastereomeric complexes

Jyoji Kurita, Fujiko Usuda, Shuji Yasuike, Takashi Tsuchiya, Yoshisuke Tsuda, Fumiyuki Kiuchi, Shinzo Hosoi

Research output: Contribution to journal › Article › peer-review

41 Citations (Scopus)

Abstract

Resolution of racemic Sb-chiral (±)-1-phenyl-2-trimethylsilylstibindole 1 has been achieved by the separation of a mixture of the diastereomeric palladium(II) complexes 3A and 3B derived from the reaction of (±)-1 with di-μ-chlorobis{(S)-2-[1-(dimethylamino)ethyl]phenyl-C,N}dipalladium(II) 2, and optically pure 1-phenylstibindoles (-)-4 and (+)-4 have also been obtained from resolved (-)-1 and (+)-1, respectively.

Original language	English
Pages (from-to)	191-192
Number of pages	2
Journal	Chemical Communications
Issue number	3
DOIs	https://doi.org/10.1039/a909200e
Publication status	Published - 2000 Feb 7
Externally published	Yes

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/a909200e

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abstract = "Resolution of racemic Sb-chiral (±)-1-phenyl-2-trimethylsilylstibindole 1 has been achieved by the separation of a mixture of the diastereomeric palladium(II) complexes 3A and 3B derived from the reaction of (±)-1 with di-μ-chlorobis{(S)-2-[1-(dimethylamino)ethyl]phenyl-C,N}dipalladium(II) 2, and optically pure 1-phenylstibindoles (-)-4 and (+)-4 have also been obtained from resolved (-)-1 and (+)-1, respectively.",

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T1 - Resolution of racemic Sb-chiral stibindoles using an optically active ortho-palladated benzylamine derivative, via their diastereomeric complexes

AU - Kurita, Jyoji

AU - Usuda, Fujiko

AU - Yasuike, Shuji

AU - Tsuchiya, Takashi

AU - Tsuda, Yoshisuke

AU - Kiuchi, Fumiyuki

AU - Hosoi, Shinzo

PY - 2000/2/7

Y1 - 2000/2/7

N2 - Resolution of racemic Sb-chiral (±)-1-phenyl-2-trimethylsilylstibindole 1 has been achieved by the separation of a mixture of the diastereomeric palladium(II) complexes 3A and 3B derived from the reaction of (±)-1 with di-μ-chlorobis{(S)-2-[1-(dimethylamino)ethyl]phenyl-C,N}dipalladium(II) 2, and optically pure 1-phenylstibindoles (-)-4 and (+)-4 have also been obtained from resolved (-)-1 and (+)-1, respectively.

AB - Resolution of racemic Sb-chiral (±)-1-phenyl-2-trimethylsilylstibindole 1 has been achieved by the separation of a mixture of the diastereomeric palladium(II) complexes 3A and 3B derived from the reaction of (±)-1 with di-μ-chlorobis{(S)-2-[1-(dimethylamino)ethyl]phenyl-C,N}dipalladium(II) 2, and optically pure 1-phenylstibindoles (-)-4 and (+)-4 have also been obtained from resolved (-)-1 and (+)-1, respectively.

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Resolution of racemic Sb-chiral stibindoles using an optically active ortho-palladated benzylamine derivative, via their diastereomeric complexes

Abstract

ASJC Scopus subject areas

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