Abstract
The enantioselective synthesis of phenanthrenol-based [9]-helicene-like molecules has been achieved via the rhodium-mediated intramolecular [2 + 2 + 2] cycloadditions of 3-phenanthrenol-linked triynes. Crystal structures and photophysical/chiroptical properties of these [9]- helicene-like molecules were compared with the corresponding [7]helicenelike molecules.
Original language | English |
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Pages (from-to) | 42-45 |
Number of pages | 4 |
Journal | Organic Letters |
Volume | 19 |
Issue number | 1 |
DOIs | |
Publication status | Published - 2017 Jan 1 |
Externally published | Yes |
ASJC Scopus subject areas
- Biochemistry
- Physical and Theoretical Chemistry
- Organic Chemistry