Abstract
The enantioselective synthesis of phenanthrenol-based [9]-helicene-like molecules has been achieved via the rhodium-mediated intramolecular [2 + 2 + 2] cycloadditions of 3-phenanthrenol-linked triynes. Crystal structures and photophysical/chiroptical properties of these [9]- helicene-like molecules were compared with the corresponding [7]helicenelike molecules.
| Original language | English |
|---|---|
| Pages (from-to) | 42-45 |
| Number of pages | 4 |
| Journal | Organic Letters |
| Volume | 19 |
| Issue number | 1 |
| DOIs | |
| Publication status | Published - 2017 Jan 1 |
| Externally published | Yes |
ASJC Scopus subject areas
- Biochemistry
- Physical and Theoretical Chemistry
- Organic Chemistry
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Yamano, R., Hara, J., Murayama, K., Sugiyama, H., Teraoka, K., Uekusa, H., Kawauchi, S., Shibata, Y., & Tanaka, K. (2017). Rh-mediated enantioselective synthesis, crystal structures, and photophysical/chiroptical properties of phenanthrenol-based [9]helicene-like molecules. Organic Letters, 19(1), 42-45. https://doi.org/10.1021/acs.orglett.6b03279