We report here a deallylative β-acylalkylation reaction of allylbenzene derivatives with allyl alcohols in the presence of Cp*Rh catalysts. Allylbenzenes possessing pyridyl and pyrazolyl directing groups were converted to β-aryl ketones via the cleavage of C(aryl)-C(allyl) bonds. Synthesis of a quinoline derivative from a β-aryl ketone product bearing a pyrazolyl group was also achieved.
|Number of pages||8|
|Journal||Journal of Organic Chemistry|
|Publication status||Published - 2023 Mar 3|
ASJC Scopus subject areas
- Organic Chemistry