Rh4S7 and Ir3CuS6 clusters with Di- and trisulfido ligands derived from dinuclear hydrogensulfido complexes

Takuya Kochi, Yoshiaki Tanabe, Zhen Tang, Youichi Ishii, Masanobu Hidai

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Abstract

Reactions of the dinuclear hydrogensulfido-bridged complexes [Cp*MCl(μ-SH)2MClCp*] (M = Rh, Ir) with CuCl2·2H2O lead to formation of Rh4S7 and Ir3CuS6 clusters [(Cp*Rh)43-S2)2(μ4-S3)][[CuCl2l2 and [(Cp*Ir)33-S2)3(CuCl 2)][CuCl2] through the oxidative S - S bond formation, the former of which contains a trisulfido ligand of the unprecedented μ42111 coordination mode.

Original languageEnglish
Pages (from-to)1279-1280
Number of pages2
JournalChemistry Letters
Issue number12
DOIs
Publication statusPublished - 1999 Jan 1
Externally publishedYes

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ASJC Scopus subject areas

  • Chemistry(all)

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