ROLE OF FLUORINE AS A CODOPANT IN CERIUM ACTIVATED SILICA GLASS.

Hiroaki Imai, K. Arai, Y. Fujino, Y. Ishii, H. Namikawa

Research output: Contribution to journalArticle

8 Citations (Scopus)

Abstract

Silica glasses codoped with cerium and fluorine were prepared by plasma torch chemical vapour deposition and the effects of fluorine on the valency and emission properties of the cerium ions were studied. Codoping with fluorine was found to have no effect on these properties, while there was a marked effect from codoping with aluminium or phosphorus, as has been reported previously. Raman spectroscopic studies showed most of the fluorine to be bonded to silicon and it is therefore concluded that fluorine neither becomes incorporated into nor influences the coordination of anions around cerium ions. The structural roles of the fluorine are discussed.

Original languageEnglish
Pages (from-to)54-58
Number of pages5
JournalPhysics and Chemistry of Glasses
Volume29
Issue number2
Publication statusPublished - 1988 Apr
Externally publishedYes

Fingerprint

Cerium
Fluorine
silica glass
Fused silica
cerium
fluorine
Ions
Plasma torches
plasma torches
Silicon
Aluminum
Phosphorus
Anions
phosphorus
Chemical vapor deposition
ions
Negative ions
vapor deposition
anions
aluminum

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Ceramics and Composites

Cite this

Imai, H., Arai, K., Fujino, Y., Ishii, Y., & Namikawa, H. (1988). ROLE OF FLUORINE AS A CODOPANT IN CERIUM ACTIVATED SILICA GLASS. Physics and Chemistry of Glasses, 29(2), 54-58.

ROLE OF FLUORINE AS A CODOPANT IN CERIUM ACTIVATED SILICA GLASS. / Imai, Hiroaki; Arai, K.; Fujino, Y.; Ishii, Y.; Namikawa, H.

In: Physics and Chemistry of Glasses, Vol. 29, No. 2, 04.1988, p. 54-58.

Research output: Contribution to journalArticle

Imai, H, Arai, K, Fujino, Y, Ishii, Y & Namikawa, H 1988, 'ROLE OF FLUORINE AS A CODOPANT IN CERIUM ACTIVATED SILICA GLASS.', Physics and Chemistry of Glasses, vol. 29, no. 2, pp. 54-58.
Imai, Hiroaki ; Arai, K. ; Fujino, Y. ; Ishii, Y. ; Namikawa, H. / ROLE OF FLUORINE AS A CODOPANT IN CERIUM ACTIVATED SILICA GLASS. In: Physics and Chemistry of Glasses. 1988 ; Vol. 29, No. 2. pp. 54-58.
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