Ruthenium-catalyzed addition of aromatic imines at the ortho C-H bonds to olefins

Fumitoshi Kakiuchi, Masakazu Yamauchi, Naoto Chatani, Shinji Murai

Research output: Contribution to journalArticle

129 Citations (Scopus)

Abstract

Additions of aromatic imines at the ortho carbon-hydrogen bonds to olefins were catalyzed by ruthenium complexes affording 1:1 addition products in good to excellent yields. In some cases, a by-product arising from dehydrogenative coupling was also obtained. Both aldimines and ketimines reacted well. Olefins such as styrene, 3,3-dimethyl-1-butene, and ethylene yielded corresponding products in good yields.

Original languageEnglish
Pages (from-to)111-112
Number of pages2
JournalChemistry Letters
Issue number2
DOIs
Publication statusPublished - 1996 Jan 1
Externally publishedYes

ASJC Scopus subject areas

  • Chemistry(all)

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