Ruthenium-catalyzed addition of aromatic imines at the ortho C-H bonds to olefins

Fumitoshi Kakiuchi; Masakazu Yamauchi; Naoto Chatani; Shinji Murai

doi:10.1246/cl.1996.111

Ruthenium-catalyzed addition of aromatic imines at the ortho C-H bonds to olefins

Fumitoshi Kakiuchi, Masakazu Yamauchi, Naoto Chatani, Shinji Murai

Research output: Contribution to journal › Article › peer-review

136 Citations (Scopus)

Abstract

Additions of aromatic imines at the ortho carbon-hydrogen bonds to olefins were catalyzed by ruthenium complexes affording 1:1 addition products in good to excellent yields. In some cases, a by-product arising from dehydrogenative coupling was also obtained. Both aldimines and ketimines reacted well. Olefins such as styrene, 3,3-dimethyl-1-butene, and ethylene yielded corresponding products in good yields.

Original language	English
Pages (from-to)	111-112
Number of pages	2
Journal	Chemistry Letters
Issue number	2
DOIs	https://doi.org/10.1246/cl.1996.111
Publication status	Published - 1996 Jan 1
Externally published	Yes

ASJC Scopus subject areas

Chemistry(all)

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10.1246/cl.1996.111

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AU - Chatani, Naoto

AU - Murai, Shinji

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Ruthenium-catalyzed addition of aromatic imines at the ortho C-H bonds to olefins

Abstract

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