Ruthenium-catalyzed dehydrogenative silylation of aryloxazolines with hydrosilanes via C-H bond cleavage

Fumitoshi Kakiuchi, Kimitaka Igi, Mitsutaka Matsumoto, Naoto Chatani, Shinji Murai

Research output: Contribution to journalArticle

87 Citations (Scopus)

Abstract

The reaction of aryloxazolines with trialkylhydrosilanes using Ru3(CO)12 or Ru(H)2(CO)(PPh3)3 complex as a catalyst resulted in dehydrogenative silylation to form ortho silylated aryloxazolines in good to excellent yields. This reaction can be applied to aryloxazolines having either electron-donating (NMe2, OMe, and CH3) or -withdrawing (CF3 and F) groups.

Original languageEnglish
Pages (from-to)422-423
Number of pages2
JournalChemistry Letters
Issue number5
DOIs
Publication statusPublished - 2001

ASJC Scopus subject areas

  • Chemistry(all)

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