Ruthenium-catalyzed dehydrogenative silylation of aryloxazolines with hydrosilanes via C-H bond cleavage

Fumitoshi Kakiuchi, Kimitaka Igi, Mitsutaka Matsumoto, Naoto Chatani, Shinji Murai

Research output: Contribution to journalArticle

83 Citations (Scopus)

Abstract

The reaction of aryloxazolines with trialkylhydrosilanes using Ru3(CO)12 or Ru(H)2(CO)(PPh3)3 complex as a catalyst resulted in dehydrogenative silylation to form ortho silylated aryloxazolines in good to excellent yields. This reaction can be applied to aryloxazolines having either electron-donating (NMe2, OMe, and CH3) or -withdrawing (CF3 and F) groups.

Original languageEnglish
Pages (from-to)422-423
Number of pages2
JournalChemistry Letters
Issue number5
Publication statusPublished - 2001
Externally publishedYes

Fingerprint

Ruthenium
Carbon Monoxide
Catalysts
Electrons

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Ruthenium-catalyzed dehydrogenative silylation of aryloxazolines with hydrosilanes via C-H bond cleavage. / Kakiuchi, Fumitoshi; Igi, Kimitaka; Matsumoto, Mitsutaka; Chatani, Naoto; Murai, Shinji.

In: Chemistry Letters, No. 5, 2001, p. 422-423.

Research output: Contribution to journalArticle

Kakiuchi, Fumitoshi ; Igi, Kimitaka ; Matsumoto, Mitsutaka ; Chatani, Naoto ; Murai, Shinji. / Ruthenium-catalyzed dehydrogenative silylation of aryloxazolines with hydrosilanes via C-H bond cleavage. In: Chemistry Letters. 2001 ; No. 5. pp. 422-423.
@article{abdafe12ae6c4752a29328d40a802d99,
title = "Ruthenium-catalyzed dehydrogenative silylation of aryloxazolines with hydrosilanes via C-H bond cleavage",
abstract = "The reaction of aryloxazolines with trialkylhydrosilanes using Ru3(CO)12 or Ru(H)2(CO)(PPh3)3 complex as a catalyst resulted in dehydrogenative silylation to form ortho silylated aryloxazolines in good to excellent yields. This reaction can be applied to aryloxazolines having either electron-donating (NMe2, OMe, and CH3) or -withdrawing (CF3 and F) groups.",
author = "Fumitoshi Kakiuchi and Kimitaka Igi and Mitsutaka Matsumoto and Naoto Chatani and Shinji Murai",
year = "2001",
language = "English",
pages = "422--423",
journal = "Chemistry Letters",
issn = "0366-7022",
publisher = "Chemical Society of Japan",
number = "5",

}

TY - JOUR

T1 - Ruthenium-catalyzed dehydrogenative silylation of aryloxazolines with hydrosilanes via C-H bond cleavage

AU - Kakiuchi, Fumitoshi

AU - Igi, Kimitaka

AU - Matsumoto, Mitsutaka

AU - Chatani, Naoto

AU - Murai, Shinji

PY - 2001

Y1 - 2001

N2 - The reaction of aryloxazolines with trialkylhydrosilanes using Ru3(CO)12 or Ru(H)2(CO)(PPh3)3 complex as a catalyst resulted in dehydrogenative silylation to form ortho silylated aryloxazolines in good to excellent yields. This reaction can be applied to aryloxazolines having either electron-donating (NMe2, OMe, and CH3) or -withdrawing (CF3 and F) groups.

AB - The reaction of aryloxazolines with trialkylhydrosilanes using Ru3(CO)12 or Ru(H)2(CO)(PPh3)3 complex as a catalyst resulted in dehydrogenative silylation to form ortho silylated aryloxazolines in good to excellent yields. This reaction can be applied to aryloxazolines having either electron-donating (NMe2, OMe, and CH3) or -withdrawing (CF3 and F) groups.

UR - http://www.scopus.com/inward/record.url?scp=0035533872&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0035533872&partnerID=8YFLogxK

M3 - Article

SP - 422

EP - 423

JO - Chemistry Letters

JF - Chemistry Letters

SN - 0366-7022

IS - 5

ER -