Ruthenium-catalyzed ortho-selective aromatic CH alkenylation with alkenyl carbonates

Yohei Ogiwara; Takuya Kochi; Fumitoshi Kakiuchi

doi:10.1246/cl.140006

Ruthenium-catalyzed ortho-selective aromatic CH alkenylation with alkenyl carbonates

Yohei Ogiwara, Takuya Kochi, Fumitoshi Kakiuchi

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

10 Citations (Scopus)

Abstract

Ortho-selective aromatic CH alkenylation with alkenyl carbonates proceeds in the presence of a catalytic amount of [Ru(cod)(cot)]. Arylpyridines and an aryloxazoline were regioselectively alkenylated without adding external bases. Aromatic CH alkylation also occurs depending on the reaction conditions.

Original language	English
Pages (from-to)	667-669
Number of pages	3
Journal	Chemistry Letters
Volume	43
Issue number	5
DOIs	https://doi.org/10.1246/cl.140006
Publication status	Published - 2014

ASJC Scopus subject areas

Chemistry(all)

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abstract = "Ortho-selective aromatic CH alkenylation with alkenyl carbonates proceeds in the presence of a catalytic amount of [Ru(cod)(cot)]. Arylpyridines and an aryloxazoline were regioselectively alkenylated without adding external bases. Aromatic CH alkylation also occurs depending on the reaction conditions.",

author = "Yohei Ogiwara and Takuya Kochi and Fumitoshi Kakiuchi",

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AB - Ortho-selective aromatic CH alkenylation with alkenyl carbonates proceeds in the presence of a catalytic amount of [Ru(cod)(cot)]. Arylpyridines and an aryloxazoline were regioselectively alkenylated without adding external bases. Aromatic CH alkylation also occurs depending on the reaction conditions.

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