Ruthenium-catalyzed ortho-selective aromatic CH alkenylation with alkenyl carbonates

Yohei Ogiwara; Takuya Kochi; Fumitoshi Kakiuchi

doi:10.1246/cl.140006

Ruthenium-catalyzed ortho-selective aromatic CH alkenylation with alkenyl carbonates

Yohei Ogiwara, Takuya Kochi, Fumitoshi Kakiuchi

Department of Chemistry

Research output: Contribution to journal › Article

10 Citations (Scopus)

Abstract

Ortho-selective aromatic CH alkenylation with alkenyl carbonates proceeds in the presence of a catalytic amount of [Ru(cod)(cot)]. Arylpyridines and an aryloxazoline were regioselectively alkenylated without adding external bases. Aromatic CH alkylation also occurs depending on the reaction conditions.

Original language	English
Pages (from-to)	667-669
Number of pages	3
Journal	Chemistry Letters
Volume	43
Issue number	5
DOIs	https://doi.org/10.1246/cl.140006
Publication status	Published - 2014

ASJC Scopus subject areas

Chemistry(all)

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10.1246/cl.140006

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Ogiwara, Y., Kochi, T., & Kakiuchi, F. (2014). Ruthenium-catalyzed ortho-selective aromatic CH alkenylation with alkenyl carbonates. Chemistry Letters, 43(5), 667-669. https://doi.org/10.1246/cl.140006

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abstract = "Ortho-selective aromatic CH alkenylation with alkenyl carbonates proceeds in the presence of a catalytic amount of [Ru(cod)(cot)]. Arylpyridines and an aryloxazoline were regioselectively alkenylated without adding external bases. Aromatic CH alkylation also occurs depending on the reaction conditions.",

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