Ruthenium-catalyzed ortho-selective aromatic CH alkenylation with alkenyl carbonates

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Abstract

Ortho-selective aromatic CH alkenylation with alkenyl carbonates proceeds in the presence of a catalytic amount of [Ru(cod)(cot)]. Arylpyridines and an aryloxazoline were regioselectively alkenylated without adding external bases. Aromatic CH alkylation also occurs depending on the reaction conditions.

Original languageEnglish
Pages (from-to)667-669
Number of pages3
JournalChemistry Letters
Volume43
Issue number5
DOIs
Publication statusPublished - 2014

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Alkenylation
Ruthenium
Carbonates
Alkylation

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Ruthenium-catalyzed ortho-selective aromatic CH alkenylation with alkenyl carbonates. / Ogiwara, Yohei; Kochi, Takuya; Kakiuchi, Fumitoshi.

In: Chemistry Letters, Vol. 43, No. 5, 2014, p. 667-669.

Research output: Contribution to journalArticle

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