Abstract
Ortho-selective aromatic CH alkenylation with alkenyl carbonates proceeds in the presence of a catalytic amount of [Ru(cod)(cot)]. Arylpyridines and an aryloxazoline were regioselectively alkenylated without adding external bases. Aromatic CH alkylation also occurs depending on the reaction conditions.
| Original language | English |
|---|---|
| Pages (from-to) | 667-669 |
| Number of pages | 3 |
| Journal | Chemistry Letters |
| Volume | 43 |
| Issue number | 5 |
| DOIs | |
| Publication status | Published - 2014 |
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- Chemistry(all)
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Ruthenium-catalyzed ortho-selective aromatic CH alkenylation with alkenyl carbonates. / Ogiwara, Yohei; Kochi, Takuya; Kakiuchi, Fumitoshi.
In: Chemistry Letters, Vol. 43, No. 5, 2014, p. 667-669.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Ruthenium-catalyzed ortho-selective aromatic CH alkenylation with alkenyl carbonates
AU - Ogiwara, Yohei
AU - Kochi, Takuya
AU - Kakiuchi, Fumitoshi
PY - 2014
Y1 - 2014
N2 - Ortho-selective aromatic CH alkenylation with alkenyl carbonates proceeds in the presence of a catalytic amount of [Ru(cod)(cot)]. Arylpyridines and an aryloxazoline were regioselectively alkenylated without adding external bases. Aromatic CH alkylation also occurs depending on the reaction conditions.
AB - Ortho-selective aromatic CH alkenylation with alkenyl carbonates proceeds in the presence of a catalytic amount of [Ru(cod)(cot)]. Arylpyridines and an aryloxazoline were regioselectively alkenylated without adding external bases. Aromatic CH alkylation also occurs depending on the reaction conditions.
UR - http://www.scopus.com/inward/record.url?scp=84899850246&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84899850246&partnerID=8YFLogxK
U2 - 10.1246/cl.140006
DO - 10.1246/cl.140006
M3 - Article
VL - 43
SP - 667
EP - 669
JO - Chemistry Letters
JF - Chemistry Letters
SN - 0366-7022
IS - 5
ER -