Selective dioxygenation of cyclohexane catalysed by hydrogen peroxide and dinuclear iron(III) complexes with μ-alkoxo bridges

Satoshi Nishino, Hiroyuki Hosomi, Shigeru Ohba, Hideaki Matsushima, Tadashi Tokii, Yuzo Nishida

Research output: Contribution to journalArticle

30 Citations (Scopus)

Abstract

Several dinuclear iron(III) complexes with μ-alkoxo bridges gave predominantly cyclohexyl hydroperoxide in the reaction with cyclohexane and hydrogen peroxide, and similar results were observed when linear n-alkanes, such as n-nonane and n-octane, were used instead of cyclohexane. A mechanism for selective formation of the hydroperoxide is discussed.

Original languageEnglish
Pages (from-to)1509-1513
Number of pages5
JournalJournal of the Chemical Society - Dalton Transactions
Issue number9
Publication statusPublished - 1999 May 7

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Hydrogen Peroxide
Iron
Alkanes
Cyclohexane
octane
nonane

ASJC Scopus subject areas

  • Inorganic Chemistry

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Selective dioxygenation of cyclohexane catalysed by hydrogen peroxide and dinuclear iron(III) complexes with μ-alkoxo bridges. / Nishino, Satoshi; Hosomi, Hiroyuki; Ohba, Shigeru; Matsushima, Hideaki; Tokii, Tadashi; Nishida, Yuzo.

In: Journal of the Chemical Society - Dalton Transactions, No. 9, 07.05.1999, p. 1509-1513.

Research output: Contribution to journalArticle

Nishino, Satoshi ; Hosomi, Hiroyuki ; Ohba, Shigeru ; Matsushima, Hideaki ; Tokii, Tadashi ; Nishida, Yuzo. / Selective dioxygenation of cyclohexane catalysed by hydrogen peroxide and dinuclear iron(III) complexes with μ-alkoxo bridges. In: Journal of the Chemical Society - Dalton Transactions. 1999 ; No. 9. pp. 1509-1513.
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