Abstract
Selective long-distance isomerization of terminal alkenes to silyl enol ethers proceeded via nondissociative chain walking using phenanthroline palladium catalysts. Notable features achieved taking advantage of the nondissociative chain walking mechanism include high efficiency obtained regardless of the chain length, high chemoselectivity toward terminal alkenes over internal ones, and retention of the stereoconfiguration of the stereocenter on the alkyl chain.
| Original language | English |
|---|---|
| Pages (from-to) | 9322-9333 |
| Number of pages | 12 |
| Journal | Journal of Organic Chemistry |
| Volume | 83 |
| Issue number | 16 |
| DOIs | |
| Publication status | Published - 2018 Aug 17 |
ASJC Scopus subject areas
- Organic Chemistry
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Cite this
Yamasaki, Y., Kumagai, T., Kanno, S., Kakiuchi, F., & Kochi, T. (2018). Selective Long-Distance Isomerization of Terminal Alkenes via Nondissociative Chain Walking. Journal of Organic Chemistry, 83(16), 9322-9333. https://doi.org/10.1021/acs.joc.8b01288