TY - JOUR
T1 - Selective Long-Distance Isomerization of Terminal Alkenes via Nondissociative Chain Walking
AU - Yamasaki, Yuya
AU - Kumagai, Takaaki
AU - Kanno, Shota
AU - Kakiuchi, Fumitoshi
AU - Kochi, Takuya
N1 - Publisher Copyright:
© 2018 American Chemical Society.
Copyright:
Copyright 2018 Elsevier B.V., All rights reserved.
PY - 2018/8/17
Y1 - 2018/8/17
N2 - Selective long-distance isomerization of terminal alkenes to silyl enol ethers proceeded via nondissociative chain walking using phenanthroline palladium catalysts. Notable features achieved taking advantage of the nondissociative chain walking mechanism include high efficiency obtained regardless of the chain length, high chemoselectivity toward terminal alkenes over internal ones, and retention of the stereoconfiguration of the stereocenter on the alkyl chain.
AB - Selective long-distance isomerization of terminal alkenes to silyl enol ethers proceeded via nondissociative chain walking using phenanthroline palladium catalysts. Notable features achieved taking advantage of the nondissociative chain walking mechanism include high efficiency obtained regardless of the chain length, high chemoselectivity toward terminal alkenes over internal ones, and retention of the stereoconfiguration of the stereocenter on the alkyl chain.
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U2 - 10.1021/acs.joc.8b01288
DO - 10.1021/acs.joc.8b01288
M3 - Article
C2 - 30022669
AN - SCOPUS:85050356658
VL - 83
SP - 9322
EP - 9333
JO - Journal of Organic Chemistry
JF - Journal of Organic Chemistry
SN - 0022-3263
IS - 16
ER -