Selective synthesis of C 3 symmetric functionalized sumanenes

Shuhei Higashibayashi, R. B. Nasir Baig, Yuki Morita, Hidehiro Sakurai

Research output: Contribution to journalArticle

19 Citations (Scopus)

Abstract

C 3 symmetric triformylsumanene was selectively synthesized from C 3 symmetric syn-tris(oxonorborneno)benzene, featuring ring-opening/closing metathesis reactions of syntris( methoxymethylnorbornadieno)benzene and DDQ oxidation. Triformylsumanene can be an intermediate to synthesize C 3 symmetric trisubstituted sumanenes by further transformation. Tris(ethoxycarbonylethenyl)sumanene was prepared through the HornerWadsworthEmmons reaction. Its optical and electrochemical behaviors were investigated.

Original languageEnglish
Pages (from-to)84-86
Number of pages3
JournalChemistry Letters
Volume41
Issue number1
DOIs
Publication statusPublished - 2012
Externally publishedYes

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Benzene
Oxidation
sumanene

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Selective synthesis of C 3 symmetric functionalized sumanenes. / Higashibayashi, Shuhei; Nasir Baig, R. B.; Morita, Yuki; Sakurai, Hidehiro.

In: Chemistry Letters, Vol. 41, No. 1, 2012, p. 84-86.

Research output: Contribution to journalArticle

Higashibayashi, Shuhei ; Nasir Baig, R. B. ; Morita, Yuki ; Sakurai, Hidehiro. / Selective synthesis of C 3 symmetric functionalized sumanenes. In: Chemistry Letters. 2012 ; Vol. 41, No. 1. pp. 84-86.
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