Self-assembled morphology of tripod nanoparticle solutions: the effect of arm length and hydrophobic ratio

Muhammad Adli Bin Sazali, Yusei Kobayashi, Yuki Taniguchi, Takuya Nakashima, Noriyoshi Arai

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

We have studied the self-assembled morphologies of tripod nanoparticle solutions confined in nanoslits using dissipative particle dynamics (DPD) simulations. In the present study, composite-shaped nanoparticles, like a planar tripod model with an amphiphilic surface pattern, were also synthesized experimentally. Using the DPD results at various values of a hydrophobic ratio (HR) and arm length (AL), we create phase diagrams of the self-assembled morphologies of tripod nanoparticles. With each of the two parameters, we observe three morphologies in the tripod nanoparticle solution. Further, potential energy vs. temperature for various tripod nanoparticle solutions is compared for different self-assembled structures. Our simulations offer a guide to control the morphologies of self-assembled tripod nanoparticles, which constitute novel systems that may find applications in nanofluidic devices.

Original languageEnglish
Pages (from-to)572-580
Number of pages9
JournalMolecular Systems Design and Engineering
Volume3
Issue number3
DOIs
Publication statusPublished - 2018 Jun 1
Externally publishedYes

ASJC Scopus subject areas

  • Chemistry (miscellaneous)
  • Chemical Engineering (miscellaneous)
  • Biomedical Engineering
  • Energy Engineering and Power Technology
  • Process Chemistry and Technology
  • Industrial and Manufacturing Engineering
  • Materials Chemistry

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