Self-assembling neodymium/sodium heterobimetallic asymmetric catalyst confined in a carbon nanotube network

Takanori Ogawa; Naoya Kumagai; Masakatsu Shibasaki

doi:10.1002/anie.201302236

Self-assembling neodymium/sodium heterobimetallic asymmetric catalyst confined in a carbon nanotube network

Takanori Ogawa, Naoya Kumagai, Masakatsu Shibasaki

Research output: Contribution to journal › Article › peer-review

60 Citations (Scopus)

Abstract

Confined cat works better: A self-assembling heterobimetallic catalyst, comprised of a Nd/Na/amide ligand confined in an entangled multiwalled carbon nanotube (MWNT) network, outperforms the unconfined catalyst in anti-selective catalytic asymmetric nitroaldol reactions. The confined catalyst could be used repeatedly through simple filtration, and was applied to a concise enantioselective synthesis of anacetrapib.

Original language	English
Pages (from-to)	6196-6201
Number of pages	6
Journal	Angewandte Chemie - International Edition
Volume	52
Issue number	24
DOIs	https://doi.org/10.1002/anie.201302236
Publication status	Published - 2013 Jun 10
Externally published	Yes

Keywords

anacetrapib
asymmetric catalysis
heterogeneous catalysts
nanotubes
nitroaldol reaction

ASJC Scopus subject areas

Catalysis
Chemistry(all)

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10.1002/anie.201302236

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AU - Kumagai, Naoya

AU - Shibasaki, Masakatsu

PY - 2013/6/10

Y1 - 2013/6/10

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KW - anacetrapib

KW - asymmetric catalysis

KW - heterogeneous catalysts

KW - nanotubes

KW - nitroaldol reaction

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Self-assembling neodymium/sodium heterobimetallic asymmetric catalyst confined in a carbon nanotube network

Abstract

Keywords

ASJC Scopus subject areas

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