Self-oscillating polymer brushes

Tsukuru Masuda, Mio Hidaka, Yoko Murase, Aya Mizutani Akimoto, Kenichi Nagase, Teruo Okano, Ryo Yoshida

Research output: Contribution to journalArticle

40 Citations (Scopus)

Abstract

An autonomous functional surface has been designed by using self-oscillating polymers that convert the chemical energy of the Belousov-Zhabotinsky reaction into conformational changes of the polymer chains (see picture: red: hydrophobic/collapsed, green: hydrophilic/extended). Self-oscillating polymer brushes were grafted onto the inner surface of a glass capillary, and autonomous propagation of a chemical wave was observed.

Original languageEnglish
Pages (from-to)7468-7471
Number of pages4
JournalAngewandte Chemie - International Edition
Volume52
Issue number29
DOIs
Publication statusPublished - 2013 Jul 15
Externally publishedYes

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Brushes
Polymers
Glass

Keywords

  • ATRP
  • functional surfaces
  • oscillating reactions
  • polymer brushes
  • ruthenium

ASJC Scopus subject areas

  • Chemistry(all)
  • Catalysis

Cite this

Masuda, T., Hidaka, M., Murase, Y., Akimoto, A. M., Nagase, K., Okano, T., & Yoshida, R. (2013). Self-oscillating polymer brushes. Angewandte Chemie - International Edition, 52(29), 7468-7471. https://doi.org/10.1002/anie.201301988

Self-oscillating polymer brushes. / Masuda, Tsukuru; Hidaka, Mio; Murase, Yoko; Akimoto, Aya Mizutani; Nagase, Kenichi; Okano, Teruo; Yoshida, Ryo.

In: Angewandte Chemie - International Edition, Vol. 52, No. 29, 15.07.2013, p. 7468-7471.

Research output: Contribution to journalArticle

Masuda, T, Hidaka, M, Murase, Y, Akimoto, AM, Nagase, K, Okano, T & Yoshida, R 2013, 'Self-oscillating polymer brushes', Angewandte Chemie - International Edition, vol. 52, no. 29, pp. 7468-7471. https://doi.org/10.1002/anie.201301988
Masuda T, Hidaka M, Murase Y, Akimoto AM, Nagase K, Okano T et al. Self-oscillating polymer brushes. Angewandte Chemie - International Edition. 2013 Jul 15;52(29):7468-7471. https://doi.org/10.1002/anie.201301988
Masuda, Tsukuru ; Hidaka, Mio ; Murase, Yoko ; Akimoto, Aya Mizutani ; Nagase, Kenichi ; Okano, Teruo ; Yoshida, Ryo. / Self-oscillating polymer brushes. In: Angewandte Chemie - International Edition. 2013 ; Vol. 52, No. 29. pp. 7468-7471.
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