Silver-catalyzed carboxylation

K. Sekine, Tohru Yamada

Research output: Contribution to journalReview article

110 Citations (Scopus)

Abstract

Silver-catalyzed reactions are some of the important methodologies in organic chemistry. Since 2007, a new application of silver catalysts has been emerging. For the sequential carboxylation and cyclization of alkyne derivatives, such as propargyl alcohols and amines, using carbon dioxide, silver catalysts show significant reactivity under mild conditions unlike other transition metals. These developments have received much attention for the effective utilization of carbon dioxide in organic chemistry to synthesize heterocyclic compounds. Related silver-catalyzed C-C bond forming reactions with carbon dioxide have also provided the synthetic methods of the corresponding carboxylic acid derivatives. In this review, the recent studies of the silver-catalyzed carboxylation reactions using carbon dioxide are described.

Original languageEnglish
Pages (from-to)4524-4532
Number of pages9
JournalChemical Society Reviews
Volume45
Issue number16
DOIs
Publication statusPublished - 2016 Aug 21

Fingerprint

Carboxylation
Silver
Carbon Dioxide
Derivatives
Heterocyclic Compounds
Catalysts
Alkynes
Cyclization
Carboxylic Acids
Amines
Transition metals

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Silver-catalyzed carboxylation. / Sekine, K.; Yamada, Tohru.

In: Chemical Society Reviews, Vol. 45, No. 16, 21.08.2016, p. 4524-4532.

Research output: Contribution to journalReview article

Sekine, K. ; Yamada, Tohru. / Silver-catalyzed carboxylation. In: Chemical Society Reviews. 2016 ; Vol. 45, No. 16. pp. 4524-4532.
@article{da19f8b246aa48a3a32a3cddf1ca7098,
title = "Silver-catalyzed carboxylation",
abstract = "Silver-catalyzed reactions are some of the important methodologies in organic chemistry. Since 2007, a new application of silver catalysts has been emerging. For the sequential carboxylation and cyclization of alkyne derivatives, such as propargyl alcohols and amines, using carbon dioxide, silver catalysts show significant reactivity under mild conditions unlike other transition metals. These developments have received much attention for the effective utilization of carbon dioxide in organic chemistry to synthesize heterocyclic compounds. Related silver-catalyzed C-C bond forming reactions with carbon dioxide have also provided the synthetic methods of the corresponding carboxylic acid derivatives. In this review, the recent studies of the silver-catalyzed carboxylation reactions using carbon dioxide are described.",
author = "K. Sekine and Tohru Yamada",
year = "2016",
month = "8",
day = "21",
doi = "10.1039/c5cs00895f",
language = "English",
volume = "45",
pages = "4524--4532",
journal = "Chemical Society Reviews",
issn = "0306-0012",
publisher = "Royal Society of Chemistry",
number = "16",

}

TY - JOUR

T1 - Silver-catalyzed carboxylation

AU - Sekine, K.

AU - Yamada, Tohru

PY - 2016/8/21

Y1 - 2016/8/21

N2 - Silver-catalyzed reactions are some of the important methodologies in organic chemistry. Since 2007, a new application of silver catalysts has been emerging. For the sequential carboxylation and cyclization of alkyne derivatives, such as propargyl alcohols and amines, using carbon dioxide, silver catalysts show significant reactivity under mild conditions unlike other transition metals. These developments have received much attention for the effective utilization of carbon dioxide in organic chemistry to synthesize heterocyclic compounds. Related silver-catalyzed C-C bond forming reactions with carbon dioxide have also provided the synthetic methods of the corresponding carboxylic acid derivatives. In this review, the recent studies of the silver-catalyzed carboxylation reactions using carbon dioxide are described.

AB - Silver-catalyzed reactions are some of the important methodologies in organic chemistry. Since 2007, a new application of silver catalysts has been emerging. For the sequential carboxylation and cyclization of alkyne derivatives, such as propargyl alcohols and amines, using carbon dioxide, silver catalysts show significant reactivity under mild conditions unlike other transition metals. These developments have received much attention for the effective utilization of carbon dioxide in organic chemistry to synthesize heterocyclic compounds. Related silver-catalyzed C-C bond forming reactions with carbon dioxide have also provided the synthetic methods of the corresponding carboxylic acid derivatives. In this review, the recent studies of the silver-catalyzed carboxylation reactions using carbon dioxide are described.

UR - http://www.scopus.com/inward/record.url?scp=84977170836&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84977170836&partnerID=8YFLogxK

U2 - 10.1039/c5cs00895f

DO - 10.1039/c5cs00895f

M3 - Review article

AN - SCOPUS:84977170836

VL - 45

SP - 4524

EP - 4532

JO - Chemical Society Reviews

JF - Chemical Society Reviews

SN - 0306-0012

IS - 16

ER -