Silver-catalyzed efficient synthesis of vinylene carbonate derivatives from carbon dioxide

Rie Ugajin, Satoshi Kikuchi, Tohru Yamada

Research output: Contribution to journalArticle

22 Citations (Scopus)

Abstract

It was found that the silver salt and base was an efficient catalytic system for the reaction of the secondary propargylic alcohol with carbon dioxide to afford various corresponding vinylene carbonate derivatives in good to high yields under mild conditions.

Original languageEnglish
Article numberST-2014-U0066-L
Pages (from-to)1178-1180
Number of pages3
JournalSynlett
Volume25
Issue number8
DOIs
Publication statusPublished - 2014 May

Keywords

  • Lewis acids
  • alkynes
  • carbon dioxide
  • isomerization
  • silver
  • vinylene carbonates

ASJC Scopus subject areas

  • Organic Chemistry

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