Silyl group transfer from allylsilanes to olefins catalyzed by a ruthenium(II) complex

Fumitoshi Kakiuchi, Airi Yamada, Naoto Chatani, Shinji Murai, Naoyuki Furukawa, Yoshio Seki

Research output: Contribution to journalArticle

30 Citations (Scopus)

Abstract

Dehydrogenative silylation of olefins, such as styrenes, methyl acrylate, and vinyl ether, using allyltriethoxysilane as the source of the silyl group can be catalyzed by RuHCl(CO)(PPh 3 ) 3 to give the corresponding vinylsilanes in good to excellent yields. The ruthenium complex also catalyzed the self-dehydrogenative silylation of allylsilanes, yielding 1,3-bis(triorganosilyl)-propenes.

Original languageEnglish
Pages (from-to)2033-2036
Number of pages4
JournalOrganometallics
Volume18
Issue number10
DOIs
Publication statusPublished - 1999 May 10
Externally publishedYes

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

Fingerprint Dive into the research topics of 'Silyl group transfer from allylsilanes to olefins catalyzed by a ruthenium(II) complex'. Together they form a unique fingerprint.

  • Cite this