Silyl group transfer from allylsilanes to olefins catalyzed by a ruthenium(II) complex

Research output: Contribution to journalArticle

29 Citations (Scopus)

Abstract

Dehydrogenative silylation of olefins, such as styrenes, methyl acrylate, and vinyl ether, using allyltriethoxysilane as the source of the silyl group can be catalyzed by RuHCl(CO)(PPh3)3 to give the corresponding vinylsilanes in good to excellent yields. The ruthenium complex also catalyzed the self-dehydrogenative silylation of allylsilanes, yielding 1,3-bis(triorganosilyl)-propenes.

Original languageEnglish
Pages (from-to)2033-2036
Number of pages4
JournalOrganometallics
Volume18
Issue number10
Publication statusPublished - 1999 May 10
Externally publishedYes

Fingerprint

Styrenes
Ruthenium
Alkenes
Carbon Monoxide
acrylates
styrenes
ruthenium
alkenes
ethers
methyl acrylate
vinylsilane
allylsilane
vinyl ether

ASJC Scopus subject areas

  • Inorganic Chemistry
  • Organic Chemistry

Cite this

Silyl group transfer from allylsilanes to olefins catalyzed by a ruthenium(II) complex. / Kakiuchi, Fumitoshi.

In: Organometallics, Vol. 18, No. 10, 10.05.1999, p. 2033-2036.

Research output: Contribution to journalArticle

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