Abstract
Methanol adsorption sites on Na nI n-1 + ions were investigated. Photoexcitation to charge-transfer states of Na nI n-1 + (methanol) predominantly produces two fragment ions: Na n-1I n-2 + (methanol) (neutral NaI loss) and Na n-1I n-2 + (neutral NaI and methanol loss), without forming Na nI n-2 + (methanol loss). The relative intensities of these fragments are correlated with the geometries and binding energies.
| Original language | English |
|---|---|
| Article number | 161101 |
| Journal | Journal of Chemical Physics |
| Volume | 123 |
| Issue number | 16 |
| DOIs | |
| Publication status | Published - 2005 Nov 7 |
| Externally published | Yes |
ASJC Scopus subject areas
- Physics and Astronomy(all)
- Physical and Theoretical Chemistry
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Cite this
Misaizu, F., Tsuruta, M., Tsunoyama, H., Furuya, A., Ohno, K., & Lintuluoto, M. (2005). Size-dependent structures of Na nI n-1 + cluster ions with a methanol adsorbate: A combined study by photodissociation spectroscopy and density-functional theory calculation. Journal of Chemical Physics, 123(16), [161101]. https://doi.org/10.1063/1.2102909