Size-dependent structures of Na nI n-1 + cluster ions with a methanol adsorbate: A combined study by photodissociation spectroscopy and density-functional theory calculation

Fuminori Misaizu; Mamoru Tsuruta; Hironori Tsunoyama; Ari Furuya; Koichi Ohno; Masami Lintuluoto

doi:10.1063/1.2102909

Size-dependent structures of Na _nI _n-1 ⁺ cluster ions with a methanol adsorbate: A combined study by photodissociation spectroscopy and density-functional theory calculation

Fuminori Misaizu, Mamoru Tsuruta, Hironori Tsunoyama, Ari Furuya, Koichi Ohno, Masami Lintuluoto

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

Methanol adsorption sites on Na _nI _n-1 ⁺ ions were investigated. Photoexcitation to charge-transfer states of Na _nI _n-1 ⁺ (methanol) predominantly produces two fragment ions: Na _n-1I _n-2 ⁺ (methanol) (neutral NaI loss) and Na _n-1I _n-2 ⁺ (neutral NaI and methanol loss), without forming Na _nI _n-2 ⁺ (methanol loss). The relative intensities of these fragments are correlated with the geometries and binding energies.

Original language	English
Article number	161101
Journal	Journal of Chemical Physics
Volume	123
Issue number	16
DOIs	https://doi.org/10.1063/1.2102909
Publication status	Published - 2005 Nov 7
Externally published	Yes

ASJC Scopus subject areas

Physics and Astronomy(all)
Physical and Theoretical Chemistry

Access to Document

10.1063/1.2102909

Fingerprint

Dive into the research topics of 'Size-dependent structures of Na nI n-1 + cluster ions with a methanol adsorbate: A combined study by photodissociation spectroscopy and density-functional theory calculation'. Together they form a unique fingerprint.

Cite this

Size-dependent structures of Na _nI _n-1 ⁺ cluster ions with a methanol adsorbate : A combined study by photodissociation spectroscopy and density-functional theory calculation. / Misaizu, Fuminori; Tsuruta, Mamoru; Tsunoyama, Hironori; Furuya, Ari; Ohno, Koichi; Lintuluoto, Masami.

In: Journal of Chemical Physics, Vol. 123, No. 16, 161101, 07.11.2005.

Research output: Contribution to journal › Article › peer-review

@article{e897eef72c094e10890cc4c81c6f5dcb,

title = "Size-dependent structures of Na nI n-1 + cluster ions with a methanol adsorbate: A combined study by photodissociation spectroscopy and density-functional theory calculation",

abstract = "Methanol adsorption sites on Na nI n-1 + ions were investigated. Photoexcitation to charge-transfer states of Na nI n-1 + (methanol) predominantly produces two fragment ions: Na n-1I n-2 + (methanol) (neutral NaI loss) and Na n-1I n-2 + (neutral NaI and methanol loss), without forming Na nI n-2 + (methanol loss). The relative intensities of these fragments are correlated with the geometries and binding energies.",

author = "Fuminori Misaizu and Mamoru Tsuruta and Hironori Tsunoyama and Ari Furuya and Koichi Ohno and Masami Lintuluoto",

year = "2005",

month = nov,

day = "7",

doi = "10.1063/1.2102909",

language = "English",

volume = "123",

journal = "Journal of Chemical Physics",

issn = "0021-9606",

publisher = "American Institute of Physics Publising LLC",

number = "16",

}

TY - JOUR

T1 - Size-dependent structures of Na nI n-1 + cluster ions with a methanol adsorbate

T2 - A combined study by photodissociation spectroscopy and density-functional theory calculation

AU - Misaizu, Fuminori

AU - Tsuruta, Mamoru

AU - Tsunoyama, Hironori

AU - Furuya, Ari

AU - Ohno, Koichi

AU - Lintuluoto, Masami

PY - 2005/11/7

Y1 - 2005/11/7

N2 - Methanol adsorption sites on Na nI n-1 + ions were investigated. Photoexcitation to charge-transfer states of Na nI n-1 + (methanol) predominantly produces two fragment ions: Na n-1I n-2 + (methanol) (neutral NaI loss) and Na n-1I n-2 + (neutral NaI and methanol loss), without forming Na nI n-2 + (methanol loss). The relative intensities of these fragments are correlated with the geometries and binding energies.

AB - Methanol adsorption sites on Na nI n-1 + ions were investigated. Photoexcitation to charge-transfer states of Na nI n-1 + (methanol) predominantly produces two fragment ions: Na n-1I n-2 + (methanol) (neutral NaI loss) and Na n-1I n-2 + (neutral NaI and methanol loss), without forming Na nI n-2 + (methanol loss). The relative intensities of these fragments are correlated with the geometries and binding energies.

UR - http://www.scopus.com/inward/record.url?scp=27344441082&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=27344441082&partnerID=8YFLogxK

U2 - 10.1063/1.2102909

DO - 10.1063/1.2102909

M3 - Article

AN - SCOPUS:27344441082

VL - 123

JO - Journal of Chemical Physics

JF - Journal of Chemical Physics

SN - 0021-9606

IS - 16

M1 - 161101

ER -