Size-dependent structures of Na nI n-1 + cluster ions with a methanol adsorbate: A combined study by photodissociation spectroscopy and density-functional theory calculation

Fuminori Misaizu, Mamoru Tsuruta, Hironori Tsunoyama, Ari Furuya, Koichi Ohno, Masami Lintuluoto

Research output: Contribution to journal › Article

2 Citations (Scopus)

Abstract

Methanol adsorption sites on Na nI n-1 + ions were investigated. Photoexcitation to charge-transfer states of Na nI n-1 + (methanol) predominantly produces two fragment ions: Na n-1I n-2 + (methanol) (neutral NaI loss) and Na n-1I n-2 + (neutral NaI and methanol loss), without forming Na nI n-2 + (methanol loss). The relative intensities of these fragments are correlated with the geometries and binding energies.

Original languageEnglish
Article number161101
JournalJournal of Chemical Physics
Volume123
Issue number16
DOIs
Publication statusPublished - 2005
Externally publishedYes

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Photodissociation
Adsorbates
photodissociation
Density functional theory
Methanol
methyl alcohol
Spectroscopy
Ions
density functional theory
spectroscopy
ions
fragments
Photoexcitation
Binding energy
photoexcitation
Charge transfer
binding energy
charge transfer
Adsorption
adsorption

ASJC Scopus subject areas

  • Atomic and Molecular Physics, and Optics

Cite this

Size-dependent structures of Na nI n-1 + cluster ions with a methanol adsorbate : A combined study by photodissociation spectroscopy and density-functional theory calculation. / Misaizu, Fuminori; Tsuruta, Mamoru; Tsunoyama, Hironori; Furuya, Ari; Ohno, Koichi; Lintuluoto, Masami.

In: Journal of Chemical Physics, Vol. 123, No. 16, 161101, 2005.

Research output: Contribution to journal › Article

Misaizu, F, Tsuruta, M, Tsunoyama, H, Furuya, A, Ohno, K & Lintuluoto, M 2005, 'Size-dependent structures of Na nI n-1 + cluster ions with a methanol adsorbate: A combined study by photodissociation spectroscopy and density-functional theory calculation', Journal of Chemical Physics, vol. 123, no. 16, 161101. https://doi.org/10.1063/1.2102909
Misaizu F, Tsuruta M, Tsunoyama H, Furuya A, Ohno K, Lintuluoto M. Size-dependent structures of Na nI n-1 + cluster ions with a methanol adsorbate: A combined study by photodissociation spectroscopy and density-functional theory calculation. Journal of Chemical Physics. 2005;123(16). 161101. https://doi.org/10.1063/1.2102909
Misaizu, Fuminori ; Tsuruta, Mamoru ; Tsunoyama, Hironori ; Furuya, Ari ; Ohno, Koichi ; Lintuluoto, Masami. / Size-dependent structures of Na nI n-1 + cluster ions with a methanol adsorbate : A combined study by photodissociation spectroscopy and density-functional theory calculation. In: Journal of Chemical Physics. 2005 ; Vol. 123, No. 16.
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