Size-dependent structures of Na nI n-1 + cluster ions with a methanol adsorbate: A combined study by photodissociation spectroscopy and density-functional theory calculation

Fuminori Misaizu, Mamoru Tsuruta, Hironori Tsunoyama, Ari Furuya, Koichi Ohno, Masami Lintuluoto

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

Methanol adsorption sites on Na nI n-1 + ions were investigated. Photoexcitation to charge-transfer states of Na nI n-1 + (methanol) predominantly produces two fragment ions: Na n-1I n-2 + (methanol) (neutral NaI loss) and Na n-1I n-2 + (neutral NaI and methanol loss), without forming Na nI n-2 + (methanol loss). The relative intensities of these fragments are correlated with the geometries and binding energies.

Original languageEnglish
Article number161101
JournalJournal of Chemical Physics
Volume123
Issue number16
DOIs
Publication statusPublished - 2005
Externally publishedYes

Fingerprint

Photodissociation
Adsorbates
photodissociation
Density functional theory
Methanol
methyl alcohol
Spectroscopy
Ions
density functional theory
spectroscopy
ions
fragments
Photoexcitation
Binding energy
photoexcitation
Charge transfer
binding energy
charge transfer
Adsorption
adsorption

ASJC Scopus subject areas

  • Atomic and Molecular Physics, and Optics

Cite this

Size-dependent structures of Na nI n-1 + cluster ions with a methanol adsorbate : A combined study by photodissociation spectroscopy and density-functional theory calculation. / Misaizu, Fuminori; Tsuruta, Mamoru; Tsunoyama, Hironori; Furuya, Ari; Ohno, Koichi; Lintuluoto, Masami.

In: Journal of Chemical Physics, Vol. 123, No. 16, 161101, 2005.

Research output: Contribution to journalArticle

@article{e897eef72c094e10890cc4c81c6f5dcb,
title = "Size-dependent structures of Na nI n-1 + cluster ions with a methanol adsorbate: A combined study by photodissociation spectroscopy and density-functional theory calculation",
abstract = "Methanol adsorption sites on Na nI n-1 + ions were investigated. Photoexcitation to charge-transfer states of Na nI n-1 + (methanol) predominantly produces two fragment ions: Na n-1I n-2 + (methanol) (neutral NaI loss) and Na n-1I n-2 + (neutral NaI and methanol loss), without forming Na nI n-2 + (methanol loss). The relative intensities of these fragments are correlated with the geometries and binding energies.",
author = "Fuminori Misaizu and Mamoru Tsuruta and Hironori Tsunoyama and Ari Furuya and Koichi Ohno and Masami Lintuluoto",
year = "2005",
doi = "10.1063/1.2102909",
language = "English",
volume = "123",
journal = "Journal of Chemical Physics",
issn = "0021-9606",
publisher = "American Institute of Physics Publising LLC",
number = "16",

}

TY - JOUR

T1 - Size-dependent structures of Na nI n-1 + cluster ions with a methanol adsorbate

T2 - A combined study by photodissociation spectroscopy and density-functional theory calculation

AU - Misaizu, Fuminori

AU - Tsuruta, Mamoru

AU - Tsunoyama, Hironori

AU - Furuya, Ari

AU - Ohno, Koichi

AU - Lintuluoto, Masami

PY - 2005

Y1 - 2005

N2 - Methanol adsorption sites on Na nI n-1 + ions were investigated. Photoexcitation to charge-transfer states of Na nI n-1 + (methanol) predominantly produces two fragment ions: Na n-1I n-2 + (methanol) (neutral NaI loss) and Na n-1I n-2 + (neutral NaI and methanol loss), without forming Na nI n-2 + (methanol loss). The relative intensities of these fragments are correlated with the geometries and binding energies.

AB - Methanol adsorption sites on Na nI n-1 + ions were investigated. Photoexcitation to charge-transfer states of Na nI n-1 + (methanol) predominantly produces two fragment ions: Na n-1I n-2 + (methanol) (neutral NaI loss) and Na n-1I n-2 + (neutral NaI and methanol loss), without forming Na nI n-2 + (methanol loss). The relative intensities of these fragments are correlated with the geometries and binding energies.

UR - http://www.scopus.com/inward/record.url?scp=27344441082&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=27344441082&partnerID=8YFLogxK

U2 - 10.1063/1.2102909

DO - 10.1063/1.2102909

M3 - Article

AN - SCOPUS:27344441082

VL - 123

JO - Journal of Chemical Physics

JF - Journal of Chemical Physics

SN - 0021-9606

IS - 16

M1 - 161101

ER -