Size-dependent structures of Na nI n-1 + cluster ions with a methanol adsorbate: A combined study by photodissociation spectroscopy and density-functional theory calculation

Fuminori Misaizu; Mamoru Tsuruta; Hironori Tsunoyama; Ari Furuya; Koichi Ohno; Masami Lintuluoto

doi:10.1063/1.2102909

Size-dependent structures of Na _nI _n-1 ⁺ cluster ions with a methanol adsorbate: A combined study by photodissociation spectroscopy and density-functional theory calculation

Fuminori Misaizu, Mamoru Tsuruta, Hironori Tsunoyama, Ari Furuya, Koichi Ohno, Masami Lintuluoto

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

Methanol adsorption sites on Na _nI _n-1 ⁺ ions were investigated. Photoexcitation to charge-transfer states of Na _nI _n-1 ⁺ (methanol) predominantly produces two fragment ions: Na _n-1I _n-2 ⁺ (methanol) (neutral NaI loss) and Na _n-1I _n-2 ⁺ (neutral NaI and methanol loss), without forming Na _nI _n-2 ⁺ (methanol loss). The relative intensities of these fragments are correlated with the geometries and binding energies.

Original language	English
Article number	161101
Journal	Journal of Chemical Physics
Volume	123
Issue number	16
DOIs	https://doi.org/10.1063/1.2102909
Publication status	Published - 2005 Nov 7
Externally published	Yes

ASJC Scopus subject areas

Physics and Astronomy(all)
Physical and Theoretical Chemistry

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Size-dependent structures of Na _nI _n-1 ⁺ cluster ions with a methanol adsorbate : A combined study by photodissociation spectroscopy and density-functional theory calculation. / Misaizu, Fuminori; Tsuruta, Mamoru; Tsunoyama, Hironori; Furuya, Ari; Ohno, Koichi; Lintuluoto, Masami.

In: Journal of Chemical Physics, Vol. 123, No. 16, 161101, 07.11.2005.

Research output: Contribution to journal › Article › peer-review

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abstract = "Methanol adsorption sites on Na nI n-1 + ions were investigated. Photoexcitation to charge-transfer states of Na nI n-1 + (methanol) predominantly produces two fragment ions: Na n-1I n-2 + (methanol) (neutral NaI loss) and Na n-1I n-2 + (neutral NaI and methanol loss), without forming Na nI n-2 + (methanol loss). The relative intensities of these fragments are correlated with the geometries and binding energies.",

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AU - Tsuruta, Mamoru

AU - Tsunoyama, Hironori

AU - Furuya, Ari

AU - Ohno, Koichi

AU - Lintuluoto, Masami

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N2 - Methanol adsorption sites on Na nI n-1 + ions were investigated. Photoexcitation to charge-transfer states of Na nI n-1 + (methanol) predominantly produces two fragment ions: Na n-1I n-2 + (methanol) (neutral NaI loss) and Na n-1I n-2 + (neutral NaI and methanol loss), without forming Na nI n-2 + (methanol loss). The relative intensities of these fragments are correlated with the geometries and binding energies.

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Size-dependent structures of Na _nI _n-1 ⁺ cluster ions with a methanol adsorbate: A combined study by photodissociation spectroscopy and density-functional theory calculation

Abstract

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