Sol-gel synthesis of inorganic complex fluorides using trifluoroacetic acid

Shinobu Fujihara, Sachiko Ono, Yoko Kishiki, Munehiro Tada, Toshio Kimura

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47 Citations (Scopus)

Abstract

A sol-gel method to prepare inorganic complex fluorides, SrAlF5 and BaMgF4 is described. Metal acetates and alkoxide were used as starting materials, and trifluoroacetic acid was used as a fluorine source. The formation of the fluorides was examined using thermal analysis, X-ray diffraction (XRD) and infrared (IR) absorption. The fluorides were formed through the highly exothermic decomposition reaction of trifluoroacetate gels at temperatures around 321-339°C. The heating time necessary to produce SrAlF5 and BaMgF4 powder samples was considerably reduced in the sol-gel process as compared to the solid-state reaction between SrF2 and AlF3 or BaF2 and MgF2. It is also shown that BaMgF4 thin films could be prepared by the sol-gel process using a spin-coating technique. The characteristics of the films were investigated with a field emission scanning electron microscope and a spectrophotometer.

Original languageEnglish
Pages (from-to)65-70
Number of pages6
JournalJournal of Fluorine Chemistry
Volume105
Issue number1
DOIs
Publication statusPublished - 2000 Jul 1

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Keywords

  • BaMgF
  • Sol-gel method
  • SrAlF
  • Thin film
  • Trifluoroacetic acid

ASJC Scopus subject areas

  • Biochemistry
  • Environmental Chemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

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