(SP-4-1 )-Bis{aqua(1R,2R)-N,N′-bis(salicylidene)-cyclohexane-1, 2-diy[diamine-κ 4O,N,N′,O′]man-ganese(III)}-di-μ-cyano-κ 4N:C-[dicyanonickel(II)]

Takashiro Akitsu, Yuiri Takeuchi, Yasuaki Einaga

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

The title compound. [Mn2Ni(C20H20N 2O2)2(CN)4(H2O) 2], is the first chiral trinuclear complex having an Mn III-NC-NiII-CN-MnIII unit. A pair of the trans sites of [Ni(CN)4]2- links two MnIII units. The MnIII ion has a pseudo-octahedral coordination geometry with the four donor atoms of the tetradentate chiral Schiff base forming the equatorial plane, and with a bridging cyanide and an aqua ligand at the axial positions.

Original languageEnglish
Pages (from-to)m502-m505
JournalActa Crystallographica Section E: Structure Reports Online
Volume61
Issue number3
DOIs
Publication statusPublished - 2005 Mar 1

    Fingerprint

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

Cite this