(SP-4-1 )-Bis{aqua(1R,2R)-N,N′-bis(salicylidene)-cyclohexane-1, 2-diy[diamine-κ 4O,N,N′,O′]man-ganese(III)}-di-μ-cyano-κ 4N: C-[dicyanonickel(II)]

Takashiro Akitsu, Yuiri Takeuchi, Yasuaki Einaga

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

The title compound. [Mn2Ni(C20H20N 2O2)2(CN)4(H2O) 2], is the first chiral trinuclear complex having an Mn III-NC-NiII-CN-MnIII unit. A pair of the trans sites of [Ni(CN)4]2- links two MnIII units. The MnIII ion has a pseudo-octahedral coordination geometry with the four donor atoms of the tetradentate chiral Schiff base forming the equatorial plane, and with a bridging cyanide and an aqua ligand at the axial positions.

Original languageEnglish
JournalActa Crystallographica Section E: Structure Reports Online
Volume61
Issue number3
DOIs
Publication statusPublished - 2005 Mar

Fingerprint

Diamines
Schiff Bases
Cyanides
cyanides
Cyclohexane
diamines
cyclohexane
imines
Ligands
Ions
Atoms
ligands
Geometry
geometry
atoms
ions
1,2-cyclohexanediamine

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Structural Biology

Cite this

@article{378be965a3074da584b138ede226fc04,
title = "(SP-4-1 )-Bis{aqua(1R,2R)-N,N′-bis(salicylidene)-cyclohexane-1, 2-diy[diamine-κ 4O,N,N′,O′]man-ganese(III)}-di-μ-cyano-κ 4N: C-[dicyanonickel(II)]",
abstract = "The title compound. [Mn2Ni(C20H20N 2O2)2(CN)4(H2O) 2], is the first chiral trinuclear complex having an Mn III-NC-NiII-CN-MnIII unit. A pair of the trans sites of [Ni(CN)4]2- links two MnIII units. The MnIII ion has a pseudo-octahedral coordination geometry with the four donor atoms of the tetradentate chiral Schiff base forming the equatorial plane, and with a bridging cyanide and an aqua ligand at the axial positions.",
author = "Takashiro Akitsu and Yuiri Takeuchi and Yasuaki Einaga",
year = "2005",
month = "3",
doi = "10.1107/S160053680500379X",
language = "English",
volume = "61",
journal = "Acta Crystallographica Section E: Structure Reports Online",
issn = "1600-5368",
publisher = "International Union of Crystallography",
number = "3",

}

TY - JOUR

T1 - (SP-4-1 )-Bis{aqua(1R,2R)-N,N′-bis(salicylidene)-cyclohexane-1, 2-diy[diamine-κ 4O,N,N′,O′]man-ganese(III)}-di-μ-cyano-κ 4N

T2 - C-[dicyanonickel(II)]

AU - Akitsu, Takashiro

AU - Takeuchi, Yuiri

AU - Einaga, Yasuaki

PY - 2005/3

Y1 - 2005/3

N2 - The title compound. [Mn2Ni(C20H20N 2O2)2(CN)4(H2O) 2], is the first chiral trinuclear complex having an Mn III-NC-NiII-CN-MnIII unit. A pair of the trans sites of [Ni(CN)4]2- links two MnIII units. The MnIII ion has a pseudo-octahedral coordination geometry with the four donor atoms of the tetradentate chiral Schiff base forming the equatorial plane, and with a bridging cyanide and an aqua ligand at the axial positions.

AB - The title compound. [Mn2Ni(C20H20N 2O2)2(CN)4(H2O) 2], is the first chiral trinuclear complex having an Mn III-NC-NiII-CN-MnIII unit. A pair of the trans sites of [Ni(CN)4]2- links two MnIII units. The MnIII ion has a pseudo-octahedral coordination geometry with the four donor atoms of the tetradentate chiral Schiff base forming the equatorial plane, and with a bridging cyanide and an aqua ligand at the axial positions.

UR - http://www.scopus.com/inward/record.url?scp=18544382253&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=18544382253&partnerID=8YFLogxK

U2 - 10.1107/S160053680500379X

DO - 10.1107/S160053680500379X

M3 - Article

AN - SCOPUS:18544382253

VL - 61

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

SN - 1600-5368

IS - 3

ER -