Spiro bis(isoxazole) as a new chiral ligand

Kazuhiko Wakita; Midori A. Arai; Takahiro Kato; Toshio Shinohara; Hiroaki Sasai

doi:10.3987/com-03-s(p)60

Spiro bis(isoxazole) as a new chiral ligand

Kazuhiko Wakita, Midori A. Arai, Takahiro Kato, Toshio Shinohara, Hiroaki Sasai

Research output: Contribution to journal › Article › peer-review

23 Citations (Scopus)

Abstract

A novel bis(isoxazole) ligand, (M*)-4,4′,5,5′,6,6′ ,7,7′-octahydro-7,7′-spirobi[benzo[c]isoxazole] (5) bearing a spiro chirality was designed and synthesized. Characterization of the ligand and its application to the enantioselective tandem cyclizaton of alkenyl alcohol via oxy-palladation are described.

Original language	English
Pages (from-to)	831-838
Number of pages	8
Journal	Heterocycles
Volume	62
DOIs	https://doi.org/10.3987/com-03-s(p)60
Publication status	Published - 2004 Jan 1
Externally published	Yes

ASJC Scopus subject areas

Analytical Chemistry
Pharmacology
Organic Chemistry

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abstract = "A novel bis(isoxazole) ligand, (M*)-4,4′,5,5′,6,6′ ,7,7′-octahydro-7,7′-spirobi[benzo[c]isoxazole] (5) bearing a spiro chirality was designed and synthesized. Characterization of the ligand and its application to the enantioselective tandem cyclizaton of alkenyl alcohol via oxy-palladation are described.",

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T1 - Spiro bis(isoxazole) as a new chiral ligand

AU - Wakita, Kazuhiko

AU - Arai, Midori A.

AU - Kato, Takahiro

AU - Shinohara, Toshio

AU - Sasai, Hiroaki

PY - 2004/1/1

Y1 - 2004/1/1

N2 - A novel bis(isoxazole) ligand, (M*)-4,4′,5,5′,6,6′ ,7,7′-octahydro-7,7′-spirobi[benzo[c]isoxazole] (5) bearing a spiro chirality was designed and synthesized. Characterization of the ligand and its application to the enantioselective tandem cyclizaton of alkenyl alcohol via oxy-palladation are described.

AB - A novel bis(isoxazole) ligand, (M*)-4,4′,5,5′,6,6′ ,7,7′-octahydro-7,7′-spirobi[benzo[c]isoxazole] (5) bearing a spiro chirality was designed and synthesized. Characterization of the ligand and its application to the enantioselective tandem cyclizaton of alkenyl alcohol via oxy-palladation are described.

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SP - 831

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JO - Heterocycles

JF - Heterocycles

ER -

Spiro bis(isoxazole) as a new chiral ligand

Abstract

ASJC Scopus subject areas

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