Stable and Highly Efficient Electrochemical Production of Formic Acid from Carbon Dioxide Using Diamond Electrodes

Keisuke Natsui, Hitomi Iwakawa, Norihito Ikemiya, Kazuya Nakata, Yasuaki Einaga

Research output: Contribution to journalArticle

43 Citations (Scopus)

Abstract

High faradaic efficiencies can be achieved in the production of formic acid (HCOOH) by metal electrodes, such as Sn or Pb, in the electrochemical reduction of carbon dioxide (CO2). However, the stability and environmental load in using them are problematic. The electrochemical reduction of CO2 to HCOOH was investigated in a flow cell using boron-doped diamond (BDD) electrodes. BDD electrodes have superior electrochemical properties to metal electrodes, and, moreover, are highly durable. The faradaic efficiency for the production of HCOOH was as high as 94.7%. Furthermore, the selectivity for the production of HCOOH was more than 99%. The rate of the production was increased to 473μmolm-2s-1 at a current density of 15mAcm-2 with a faradaic efficiency of 61%. The faradaic efficiency and the production rate are almost the same as or larger than those achieved using Sn and Pb electrodes. Furthermore, the stability of the BDD electrodes was confirmed by 24h operation.

Original languageEnglish
JournalAngewandte Chemie - International Edition
DOIs
Publication statusAccepted/In press - 2018 Jan 1

Fingerprint

formic acid
Diamond
Formic acid
Carbon Dioxide
Diamonds
Carbon dioxide
Electrodes
Boron
Metals
Electrochemical properties
Current density

Keywords

  • Boron
  • Carbon dioxide
  • Diamond
  • Electrochemistry
  • Formic acid

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

Cite this

Stable and Highly Efficient Electrochemical Production of Formic Acid from Carbon Dioxide Using Diamond Electrodes. / Natsui, Keisuke; Iwakawa, Hitomi; Ikemiya, Norihito; Nakata, Kazuya; Einaga, Yasuaki.

In: Angewandte Chemie - International Edition, 01.01.2018.

Research output: Contribution to journalArticle

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AU - Einaga, Yasuaki

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