Stepwise construction of a Re-Pd heterodinuclear core inside the cavity of p-tBu-calix[4]arene

Kentarou Iwasa; Takuya Kochi; Youichi Ishii

doi:10.1002/anie.200351530

Stepwise construction of a Re-Pd heterodinuclear core inside the cavity of p-tBu-calix[4]arene

Kentarou Iwasa, Takuya Kochi, Youichi Ishii

Research output: Contribution to journal › Article › peer-review

18 Citations (Scopus)

Abstract

A Re-Pd heterometallic core has been constructed inside the cavity of a calixarene ligand. An unprecedented calix[4]-arene-rhenium complex can incorporate a {Pd(η3-C₃H_s)⁺} fragment to afford the phenoxo-bridged heterodinuclear complex [ReO₂{p-t Bu-calix[4]arene-(O)₄} Pd (η³-C₃H ₅)] (see picture).

Original language	English
Pages (from-to)	3658-3660
Number of pages	3
Journal	Angewandte Chemie - International Edition
Volume	42
Issue number	31
DOIs	https://doi.org/10.1002/anie.200351530
Publication status	Published - 2003 Aug 11
Externally published	Yes

Keywords

Bimetallic complexes
Calixarenes
Palladium
Rhenium
Transition metals

ASJC Scopus subject areas

Catalysis
Chemistry(all)

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10.1002/anie.200351530

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abstract = "A Re-Pd heterometallic core has been constructed inside the cavity of a calixarene ligand. An unprecedented calix[4]-arene-rhenium complex can incorporate a {Pd(η3-C3Hs)+} fragment to afford the phenoxo-bridged heterodinuclear complex [ReO2{p-t Bu-calix[4]arene-(O)4} Pd (η3-C3H 5)] (see picture).",

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AU - Kochi, Takuya

AU - Ishii, Youichi

PY - 2003/8/11

Y1 - 2003/8/11

N2 - A Re-Pd heterometallic core has been constructed inside the cavity of a calixarene ligand. An unprecedented calix[4]-arene-rhenium complex can incorporate a {Pd(η3-C3Hs)+} fragment to afford the phenoxo-bridged heterodinuclear complex [ReO2{p-t Bu-calix[4]arene-(O)4} Pd (η3-C3H 5)] (see picture).

AB - A Re-Pd heterometallic core has been constructed inside the cavity of a calixarene ligand. An unprecedented calix[4]-arene-rhenium complex can incorporate a {Pd(η3-C3Hs)+} fragment to afford the phenoxo-bridged heterodinuclear complex [ReO2{p-t Bu-calix[4]arene-(O)4} Pd (η3-C3H 5)] (see picture).

KW - Bimetallic complexes

KW - Calixarenes

KW - Palladium

KW - Rhenium

KW - Transition metals

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JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

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ER -

Stepwise construction of a Re-Pd heterodinuclear core inside the cavity of p-tBu-calix[4]arene

Abstract

Keywords

ASJC Scopus subject areas

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