Stepwise construction of a Re-Pd heterodinuclear core inside the cavity of p-tBu-calix[4]arene

Kentarou Iwasa, Takuya Kochi, Youichi Ishii

Research output: Contribution to journalArticle

15 Citations (Scopus)

Abstract

A Re-Pd heterometallic core has been constructed inside the cavity of a calixarene ligand. An unprecedented calix[4]-arene-rhenium complex can incorporate a {Pd(η3-C3Hs)+} fragment to afford the phenoxo-bridged heterodinuclear complex [ReO2{p-t Bu-calix[4]arene-(O)4} Pd (η3-C3H 5)] (see picture).

Original languageEnglish
Pages (from-to)3658-3660
Number of pages3
JournalAngewandte Chemie - International Edition
Volume42
Issue number31
DOIs
Publication statusPublished - 2003 Aug 11
Externally publishedYes

Keywords

  • Bimetallic complexes
  • Calixarenes
  • Palladium
  • Rhenium
  • Transition metals

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

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