Stereochemistry in dehydrogenation of 3α, 7α, 12α-trihydroxy-5β-cholestan-26-oyl CoA during cholic acid biosynthesis

Masatoshi Yuri, Noriyuki Hara, Yoshinori Fujimoto, Noriko Kobayashi, Chiaki Hagiwara, Masuo Morisaki

Research output: Contribution to journalArticlepeer-review

1 Citation (Scopus)

Abstract

The dehydrogenation reaction, catalysed by 3α, 7α, 12α-trihydroxy-5β-cholestan-26-oyl CoA oxidase, is elucidated to proceed via syn-elimination of [24-pro-R]-hydrogen and 25-hydrogen.

Original languageEnglish
Pages (from-to)2325-2326
Number of pages2
JournalJournal of the Chemical Society, Chemical Communications
Issue number20
DOIs
Publication statusPublished - 1994 Dec 1

ASJC Scopus subject areas

  • Molecular Medicine

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