Stereoselective α-hydrazination of α,β-unsaturated carboxylates catalyzed by Manganese(III) complex with dialkylazodicarboxylate and phenylsilane

Mitsuo Sato; Yasuhiko Gunji; Taketo Ikeno; Tohru Yamada

doi:10.1246/cl.2005.316

Stereoselective α-hydrazination of α,β-unsaturated carboxylates catalyzed by Manganese(III) complex with dialkylazodicarboxylate and phenylsilane

Mitsuo Sato, Yasuhiko Gunji, Taketo Ikeno, Tohru Yamada

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

15 Citations (Scopus)

Abstract

In the presence of a catalytic amount of bis(dipivaloylmethanato) manganese(III) complex, the α,β-unsaturated carboxylates with camphorsultam as a chiral auxiliary reacted with phenylsilane and dialkyl azodicarboxylates to afford the corresponding α-hydrazinated carboxylates with high stereoselectivities.

Original language	English
Pages (from-to)	316-317
Number of pages	2
Journal	Chemistry Letters
Volume	34
Issue number	3
DOIs	https://doi.org/10.1246/cl.2005.316
Publication status	Published - 2005 Mar 5

ASJC Scopus subject areas

Chemistry(all)

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title = "Stereoselective α-hydrazination of α,β-unsaturated carboxylates catalyzed by Manganese(III) complex with dialkylazodicarboxylate and phenylsilane",

abstract = "In the presence of a catalytic amount of bis(dipivaloylmethanato) manganese(III) complex, the α,β-unsaturated carboxylates with camphorsultam as a chiral auxiliary reacted with phenylsilane and dialkyl azodicarboxylates to afford the corresponding α-hydrazinated carboxylates with high stereoselectivities.",

author = "Mitsuo Sato and Yasuhiko Gunji and Taketo Ikeno and Tohru Yamada",

year = "2005",

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journal = "Chemistry Letters",

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T1 - Stereoselective α-hydrazination of α,β-unsaturated carboxylates catalyzed by Manganese(III) complex with dialkylazodicarboxylate and phenylsilane

AU - Sato, Mitsuo

AU - Gunji, Yasuhiko

AU - Ikeno, Taketo

AU - Yamada, Tohru

PY - 2005/3/5

Y1 - 2005/3/5

N2 - In the presence of a catalytic amount of bis(dipivaloylmethanato) manganese(III) complex, the α,β-unsaturated carboxylates with camphorsultam as a chiral auxiliary reacted with phenylsilane and dialkyl azodicarboxylates to afford the corresponding α-hydrazinated carboxylates with high stereoselectivities.

AB - In the presence of a catalytic amount of bis(dipivaloylmethanato) manganese(III) complex, the α,β-unsaturated carboxylates with camphorsultam as a chiral auxiliary reacted with phenylsilane and dialkyl azodicarboxylates to afford the corresponding α-hydrazinated carboxylates with high stereoselectivities.

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DO - 10.1246/cl.2005.316

M3 - Article

AN - SCOPUS:19444388114

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JF - Chemistry Letters

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IS - 3

ER -

Stereoselective α-hydrazination of α,β-unsaturated carboxylates catalyzed by Manganese(III) complex with dialkylazodicarboxylate and phenylsilane

Abstract

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