Stereoselective α-hydrazination of α,β-unsaturated carboxylates catalyzed by Manganese(III) complex with dialkylazodicarboxylate and phenylsilane

Mitsuo Sato, Yasuhiko Gunji, Taketo Ikeno, Tohru Yamada

Research output: Contribution to journal › Article

14 Citations (Scopus)

Abstract

In the presence of a catalytic amount of bis(dipivaloylmethanato) manganese(III) complex, the α,β-unsaturated carboxylates with camphorsultam as a chiral auxiliary reacted with phenylsilane and dialkyl azodicarboxylates to afford the corresponding α-hydrazinated carboxylates with high stereoselectivities.

Original languageEnglish
Pages (from-to)316-317
Number of pages2
JournalChemistry Letters
Volume34
Issue number3
DOIs
Publication statusPublished - 2005 Mar 5

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Stereoselectivity
Manganese
camphorsultam

ASJC Scopus subject areas

  • Chemistry(all)

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Stereoselective α-hydrazination of α,β-unsaturated carboxylates catalyzed by Manganese(III) complex with dialkylazodicarboxylate and phenylsilane. / Sato, Mitsuo; Gunji, Yasuhiko; Ikeno, Taketo; Yamada, Tohru.

In: Chemistry Letters, Vol. 34, No. 3, 05.03.2005, p. 316-317.

Research output: Contribution to journal › Article

Sato, M, Gunji, Y, Ikeno, T & Yamada, T 2005, 'Stereoselective α-hydrazination of α,β-unsaturated carboxylates catalyzed by Manganese(III) complex with dialkylazodicarboxylate and phenylsilane', Chemistry Letters, vol. 34, no. 3, pp. 316-317. https://doi.org/10.1246/cl.2005.316
Sato M, Gunji Y, Ikeno T, Yamada T. Stereoselective α-hydrazination of α,β-unsaturated carboxylates catalyzed by Manganese(III) complex with dialkylazodicarboxylate and phenylsilane. Chemistry Letters. 2005 Mar 5;34(3):316-317. https://doi.org/10.1246/cl.2005.316
Sato, Mitsuo ; Gunji, Yasuhiko ; Ikeno, Taketo ; Yamada, Tohru. / Stereoselective α-hydrazination of α,β-unsaturated carboxylates catalyzed by Manganese(III) complex with dialkylazodicarboxylate and phenylsilane. In: Chemistry Letters. 2005 ; Vol. 34, No. 3. pp. 316-317.
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