Stereoselective α-hydrazination of α,β-unsaturated carboxylates catalyzed by Manganese(III) complex with dialkylazodicarboxylate and phenylsilane

Mitsuo Sato, Yasuhiko Gunji, Taketo Ikeno, Tohru Yamada

Research output: Contribution to journalArticle

14 Citations (Scopus)

Abstract

In the presence of a catalytic amount of bis(dipivaloylmethanato) manganese(III) complex, the α,β-unsaturated carboxylates with camphorsultam as a chiral auxiliary reacted with phenylsilane and dialkyl azodicarboxylates to afford the corresponding α-hydrazinated carboxylates with high stereoselectivities.

Original languageEnglish
Pages (from-to)316-317
Number of pages2
JournalChemistry Letters
Volume34
Issue number3
DOIs
Publication statusPublished - 2005 Mar 5

ASJC Scopus subject areas

  • Chemistry(all)

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