Stereoselective chlorination of steroidal 5,6-olefin by an electrochemical method; a convenient synthesis of blattelastanoside B

Shojiro Maki; Katsuhiro Konno; Shigeru Ohba; Hiroaki Takayama

doi:10.1016/S0040-4039(98)00538-3

Stereoselective chlorination of steroidal 5,6-olefin by an electrochemical method; a convenient synthesis of blattelastanoside B

Shojiro Maki, Katsuhiro Konno, Shigeru Ohba, Hiroaki Takayama

Department of Humanities and Social Sciences

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

Stereoselective chlorination of cholesterol (1) was achieved by an electrochemical method to give a dichloride 2 and a cholohydrin 3. Using this procedure, blattelastanoside B (6), an aggregation pheromone of the German cockroach, was synthesized from β-sitosterol (5') in short steps.

Original language	English
Pages (from-to)	3541-3542
Number of pages	2
Journal	Tetrahedron Letters
Volume	39
Issue number	21
DOIs	https://doi.org/10.1016/S0040-4039(98)00538-3
Publication status	Published - 1998 May 21

ASJC Scopus subject areas

Biochemistry
Drug Discovery
Organic Chemistry

Access to Document

10.1016/S0040-4039(98)00538-3

Cite this

@article{4d999ed316604d95a4e5c824aa4dcaf4,

title = "Stereoselective chlorination of steroidal 5,6-olefin by an electrochemical method; a convenient synthesis of blattelastanoside B",

abstract = "Stereoselective chlorination of cholesterol (1) was achieved by an electrochemical method to give a dichloride 2 and a cholohydrin 3. Using this procedure, blattelastanoside B (6), an aggregation pheromone of the German cockroach, was synthesized from β-sitosterol (5') in short steps.",

author = "Shojiro Maki and Katsuhiro Konno and Shigeru Ohba and Hiroaki Takayama",

year = "1998",

month = may,

day = "21",

doi = "10.1016/S0040-4039(98)00538-3",

language = "English",

volume = "39",

pages = "3541--3542",

journal = "Tetrahedron Letters",

issn = "0040-4039",

publisher = "Elsevier Limited",

number = "21",

}

TY - JOUR

T1 - Stereoselective chlorination of steroidal 5,6-olefin by an electrochemical method; a convenient synthesis of blattelastanoside B

AU - Maki, Shojiro

AU - Konno, Katsuhiro

AU - Ohba, Shigeru

AU - Takayama, Hiroaki

PY - 1998/5/21

Y1 - 1998/5/21

N2 - Stereoselective chlorination of cholesterol (1) was achieved by an electrochemical method to give a dichloride 2 and a cholohydrin 3. Using this procedure, blattelastanoside B (6), an aggregation pheromone of the German cockroach, was synthesized from β-sitosterol (5') in short steps.

AB - Stereoselective chlorination of cholesterol (1) was achieved by an electrochemical method to give a dichloride 2 and a cholohydrin 3. Using this procedure, blattelastanoside B (6), an aggregation pheromone of the German cockroach, was synthesized from β-sitosterol (5') in short steps.

UR - http://www.scopus.com/inward/record.url?scp=0032555007&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0032555007&partnerID=8YFLogxK

U2 - 10.1016/S0040-4039(98)00538-3

DO - 10.1016/S0040-4039(98)00538-3

M3 - Article

AN - SCOPUS:0032555007

SN - 0040-4039

VL - 39

SP - 3541

EP - 3542

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 21

ER -

Stereoselective chlorination of steroidal 5,6-olefin by an electrochemical method; a convenient synthesis of blattelastanoside B

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this