Stereoselective preparation of α-hydroxycarboxamide by manganese complex catalyzed hydration of α,β-unsaturated carboxamide with molecular oxygen and phenylsilane

Mitsuo Sato, Yasuhiko Gunji, Taketo Ikeno, Tohru Yamada

Research output: Contribution to journalArticle

10 Citations (Scopus)

Abstract

Aerobic oxidation with the combined use of phenylsilane and a manganese complex catalyst was successfully applied to the α,β-unsaturated carboxamide containing a C2-symmetrical chiral auxiliary to afford the corresponding α-hydroxycarboxamide in good-to-high yield with high stereoselectivity.

Original languageEnglish
Article numberCL-040824
Pages (from-to)1304-1305
Number of pages2
JournalChemistry Letters
Volume33
Issue number10
DOIs
Publication statusPublished - 2004 Oct 5

ASJC Scopus subject areas

  • Chemistry(all)

Fingerprint Dive into the research topics of 'Stereoselective preparation of α-hydroxycarboxamide by manganese complex catalyzed hydration of α,β-unsaturated carboxamide with molecular oxygen and phenylsilane'. Together they form a unique fingerprint.

  • Cite this