Stereoselective preparation of α-hydroxycarboxamide by manganese complex catalyzed hydration of α,β-unsaturated carboxamide with molecular oxygen and phenylsilane

Mitsuo Sato, Yasuhiko Gunji, Taketo Ikeno, Tohru Yamada

Research output: Contribution to journalArticle

8 Citations (Scopus)

Abstract

Aerobic oxidation with the combined use of phenylsilane and a manganese complex catalyst was successfully applied to the α,β-unsaturated carboxamide containing a C2-symmetrical chiral auxiliary to afford the corresponding α-hydroxycarboxamide in good-to-high yield with high stereoselectivity.

Original languageEnglish
Article numberCL-040824
Pages (from-to)1304-1305
Number of pages2
JournalChemistry Letters
Volume33
Issue number10
DOIs
Publication statusPublished - 2004 Oct 5

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Stereoselectivity
Molecular oxygen
Manganese
Hydration
Oxidation
Catalysts

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Stereoselective preparation of α-hydroxycarboxamide by manganese complex catalyzed hydration of α,β-unsaturated carboxamide with molecular oxygen and phenylsilane. / Sato, Mitsuo; Gunji, Yasuhiko; Ikeno, Taketo; Yamada, Tohru.

In: Chemistry Letters, Vol. 33, No. 10, CL-040824, 05.10.2004, p. 1304-1305.

Research output: Contribution to journalArticle

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