Stereoselective synthesis of the LM ring moiety of ciguatoxin: Reagent control of asymmetric dihydroxylation

Tohru Oishi; Mitsuru Shoji; Naomi Kumahara; Masahiro Hirama

doi:10.1246/cl.1997.845

Stereoselective synthesis of the LM ring moiety of ciguatoxin: Reagent control of asymmetric dihydroxylation

Tohru Oishi, Mitsuru Shoji, Naomi Kumahara, Masahiro Hirama

School of Pharmaceutical Sciences

Research output: Contribution to journal › Article

34 Citations (Scopus)

Abstract

Stereoselective synthesis of the LM ring moiety of ciguatoxin was achieved from (R)-(E)-1-benzyloxy-2-hydroxy-3-pentene via Ireland-Claisen rearrangement, iodolactonization, and reagent-controlled asymmetric dihydroxylation.

Original language	English
Pages (from-to)	845-846
Number of pages	2
Journal	Chemistry Letters
Issue number	9
DOIs	https://doi.org/10.1246/cl.1997.845
Publication status	Published - 1997 Jan 1

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Chemistry(all)

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Oishi, T., Shoji, M., Kumahara, N., & Hirama, M. (1997). Stereoselective synthesis of the LM ring moiety of ciguatoxin: Reagent control of asymmetric dihydroxylation. Chemistry Letters, (9), 845-846. https://doi.org/10.1246/cl.1997.845

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10.1246/cl.1997.845