Stereoselective synthesis of the LM ring moiety of ciguatoxin: Reagent control of asymmetric dihydroxylation

Tohru Oishi; Mitsuru Shoji; Naomi Kumahara; Masahiro Hirama

doi:10.1246/cl.1997.845

Stereoselective synthesis of the LM ring moiety of ciguatoxin: Reagent control of asymmetric dihydroxylation

Tohru Oishi, Mitsuru Shoji, Naomi Kumahara, Masahiro Hirama

School of Pharmaceutical Sciences

Research output: Contribution to journal › Article › peer-review

34 Citations (Scopus)

Abstract

Stereoselective synthesis of the LM ring moiety of ciguatoxin was achieved from (R)-(E)-1-benzyloxy-2-hydroxy-3-pentene via Ireland-Claisen rearrangement, iodolactonization, and reagent-controlled asymmetric dihydroxylation.

Original language	English
Pages (from-to)	845-846
Number of pages	2
Journal	Chemistry Letters
Issue number	9
DOIs	https://doi.org/10.1246/cl.1997.845
Publication status	Published - 1997 Jan 1

ASJC Scopus subject areas

Chemistry(all)

Access to Document

10.1246/cl.1997.845

Cite this

@article{244fb5d4ff2c40f19cd3adbf99520359,

title = "Stereoselective synthesis of the LM ring moiety of ciguatoxin: Reagent control of asymmetric dihydroxylation",

abstract = "Stereoselective synthesis of the LM ring moiety of ciguatoxin was achieved from (R)-(E)-1-benzyloxy-2-hydroxy-3-pentene via Ireland-Claisen rearrangement, iodolactonization, and reagent-controlled asymmetric dihydroxylation.",

author = "Tohru Oishi and Mitsuru Shoji and Naomi Kumahara and Masahiro Hirama",

year = "1997",

month = jan,

day = "1",

doi = "10.1246/cl.1997.845",

language = "English",

pages = "845--846",

journal = "Chemistry Letters",

issn = "0366-7022",

publisher = "Chemical Society of Japan",

number = "9",

}

TY - JOUR

T1 - Stereoselective synthesis of the LM ring moiety of ciguatoxin

T2 - Reagent control of asymmetric dihydroxylation

AU - Oishi, Tohru

AU - Shoji, Mitsuru

AU - Kumahara, Naomi

AU - Hirama, Masahiro

PY - 1997/1/1

Y1 - 1997/1/1

N2 - Stereoselective synthesis of the LM ring moiety of ciguatoxin was achieved from (R)-(E)-1-benzyloxy-2-hydroxy-3-pentene via Ireland-Claisen rearrangement, iodolactonization, and reagent-controlled asymmetric dihydroxylation.

AB - Stereoselective synthesis of the LM ring moiety of ciguatoxin was achieved from (R)-(E)-1-benzyloxy-2-hydroxy-3-pentene via Ireland-Claisen rearrangement, iodolactonization, and reagent-controlled asymmetric dihydroxylation.

UR - http://www.scopus.com/inward/record.url?scp=0031317275&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0031317275&partnerID=8YFLogxK

U2 - 10.1246/cl.1997.845

DO - 10.1246/cl.1997.845

M3 - Article

AN - SCOPUS:0031317275

SP - 845

EP - 846

JO - Chemistry Letters

JF - Chemistry Letters

SN - 0366-7022

IS - 9

ER -

Stereoselective synthesis of the LM ring moiety of ciguatoxin: Reagent control of asymmetric dihydroxylation

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this