Stereoselective total synthesis of (+)-myriocin from D-mannose

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Abstract

The stereoselective total synthesis of myriocin 1 from Dmannose is described; the carbon framework with three contiguous chiral centers including a tetra-substituted carbon with nitrogen was effectively constructed using Overman rearrangement as the key reaction.

Original languageEnglish
Pages (from-to)1932-1933
Number of pages2
JournalChemical Communications
Volume1
Issue number19
DOIs
Publication statusPublished - 2001 Jan 1

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ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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