Structural properties of Li1+xV3O8 upon lithium insertion at ambient and high temperature

Jin Kawakita; Yasushi Katayama; Takashi Miura; Tomiya Kishi

doi:10.1016/s0167-2738(97)00523-7

Structural properties of Li_1+xV₃O₈ upon lithium insertion at ambient and high temperature

Jin Kawakita, Yasushi Katayama, Takashi Miura, Tomiya Kishi

Department of Applied Chemistry

Research output: Contribution to journal › Article › peer-review

42 Citations (Scopus)

Abstract

Lithium insertion behaviour of lithium vanadate, Li_1.2V₃O₈, was investigated using both chemical and electrochemical methods at ambient and high temperature of 100°C. Additional Li⁺ ions up to Li₄V₃O₈ were accommodated under 2.5 V at 100°C. Each of the cell parameters changed linearly in the single-phase region of x < 2.0 in Li_1+xV₃O₈. A constant value was observed in the two-phase region of 2.0 < x < 3.0. Further lithium insertion beyond x > 3.2 lead to an increase in cell volume of the host structure.

Original language	English
Pages (from-to)	145-152
Number of pages	8
Journal	Solid State Ionics
Volume	107
Issue number	1-2
DOIs	https://doi.org/10.1016/s0167-2738(97)00523-7
Publication status	Published - 1998 Mar 1

Keywords

Cell parameters
Lithium insertion
Lithium vanadate
Temperature

ASJC Scopus subject areas

Chemistry(all)
Materials Science(all)
Condensed Matter Physics

Access to Document

10.1016/s0167-2738(97)00523-7

Cite this

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title = "Structural properties of Li1+xV3O8 upon lithium insertion at ambient and high temperature",

abstract = "Lithium insertion behaviour of lithium vanadate, Li1.2V3O8, was investigated using both chemical and electrochemical methods at ambient and high temperature of 100°C. Additional Li+ ions up to Li4V3O8 were accommodated under 2.5 V at 100°C. Each of the cell parameters changed linearly in the single-phase region of x < 2.0 in Li1+xV3O8. A constant value was observed in the two-phase region of 2.0 < x < 3.0. Further lithium insertion beyond x > 3.2 lead to an increase in cell volume of the host structure.",

keywords = "Cell parameters, Lithium insertion, Lithium vanadate, Temperature",

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T1 - Structural properties of Li1+xV3O8 upon lithium insertion at ambient and high temperature

AU - Kawakita, Jin

AU - Katayama, Yasushi

AU - Miura, Takashi

AU - Kishi, Tomiya

PY - 1998/3/1

Y1 - 1998/3/1

N2 - Lithium insertion behaviour of lithium vanadate, Li1.2V3O8, was investigated using both chemical and electrochemical methods at ambient and high temperature of 100°C. Additional Li+ ions up to Li4V3O8 were accommodated under 2.5 V at 100°C. Each of the cell parameters changed linearly in the single-phase region of x < 2.0 in Li1+xV3O8. A constant value was observed in the two-phase region of 2.0 < x < 3.0. Further lithium insertion beyond x > 3.2 lead to an increase in cell volume of the host structure.

AB - Lithium insertion behaviour of lithium vanadate, Li1.2V3O8, was investigated using both chemical and electrochemical methods at ambient and high temperature of 100°C. Additional Li+ ions up to Li4V3O8 were accommodated under 2.5 V at 100°C. Each of the cell parameters changed linearly in the single-phase region of x < 2.0 in Li1+xV3O8. A constant value was observed in the two-phase region of 2.0 < x < 3.0. Further lithium insertion beyond x > 3.2 lead to an increase in cell volume of the host structure.

KW - Cell parameters

KW - Lithium insertion

KW - Lithium vanadate

KW - Temperature

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