Structural study of hexanethiolate on Au(1 1 1) in the 'striped' phase

Toru Shimada, Hiroshi Kondoh, Ikuyo Nakai, Masanari Nagasaka, Reona Yokota, Kenta Amemiya, Toshiaki Ohta

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22 Citations (Scopus)


We have studied the structure of the 'striped' (flat-lying) phase of hexanethiolate on Au(1 1 1) by using X-ray photoelectron spectroscopy, near edge X-ray absorption fine structure and scanned-energy photoelectron diffraction. Combined results of these techniques indicate that gaseous hexanethiol adsorbs as hexanethiolate in the 'striped' phase with the alkyl chain lying down onto the surface and the S head group occupying an atop site. The S-Au distance was determined to be 2.40 ± 0.05 Å. The present experiments clearly exclude both the multiple-site model and the dimer model.

Original languageEnglish
Pages (from-to)232-236
Number of pages5
JournalChemical Physics Letters
Issue number1-3
Publication statusPublished - 2005 Apr 23
Externally publishedYes

ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

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    Shimada, T., Kondoh, H., Nakai, I., Nagasaka, M., Yokota, R., Amemiya, K., & Ohta, T. (2005). Structural study of hexanethiolate on Au(1 1 1) in the 'striped' phase. Chemical Physics Letters, 406(1-3), 232-236.