Structural, thermal and rheological studies on newly developed polyesters randomly copolymerized with poly (tetramethylene glycol) (PTMG)

Osamu Matsumoto, Atsushi Hotta

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

Poly (cyclohexanedimethanol cyclohexanedicarboxlic acid) (PCC), a fairly newly synthesized polyester, has been studied. Having a good experience of increasing both thermal stability and service temperature when applied to typical polymers, poly (tetramethylene glycol) (PTMG) was selected as a softening agent that was randomly copolymerized into the PCC chains. Another widely-used polyester, poly (ethylene terephthalate) (PET) was also produced in order to investigate the effect of PTMG, which was compared with the properties of the newly developed random PCC-PTMG copolymers (PCCP). In this study, the crystalline structures, the thermal and the mechanical properties of both PCC and PET containing different ratios of the random segment of PTMG were investigated by differential scanning calorimetery (DSC) and tensile tester. It was found that the crystallization rate of pure PCC was significantly slow, whereas for PCCP, PTMG effectively accelerated the crystallization rate with increasing PTMG, and the sample with 25 wt% of PTMG had the fastest crystallization rate in all PCCP samples. Here, the PTMG acted as an accelerator, simultaneously depressing the movement of PCC molecular chains. The elastic recovery test indicated that the ability of PTMG as a softening agent was highly demonstrated at 20 wt% of PTMG. The results of PCCP were compared with those of PET-PTMG copolymers (PETP) and it was found that there were optimum values of PTMG for the crystallization rate on both samples. Additionally, the results of the elastic recovery test indicated that the softening effects observed in PCCP were more pronounced than those observed in PETP.

Original languageEnglish
Title of host publicationSelecting and Qualifying New Materials for Use in Regulated Industries
Pages43-48
Number of pages6
Publication statusPublished - 2008 Dec 1
Event2008 MRS Fall Meeting - Boston, MA, United States
Duration: 2008 Dec 12008 Dec 5

Publication series

NameMaterials Research Society Symposium Proceedings
Volume1151
ISSN (Print)0272-9172

Other

Other2008 MRS Fall Meeting
CountryUnited States
CityBoston, MA
Period08/12/108/12/5

ASJC Scopus subject areas

  • Materials Science(all)
  • Condensed Matter Physics
  • Mechanics of Materials
  • Mechanical Engineering

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    Matsumoto, O., & Hotta, A. (2008). Structural, thermal and rheological studies on newly developed polyesters randomly copolymerized with poly (tetramethylene glycol) (PTMG). In Selecting and Qualifying New Materials for Use in Regulated Industries (pp. 43-48). (Materials Research Society Symposium Proceedings; Vol. 1151).