Structural, XPS and impedance analysis of LixCoVO4 (x = 0.8, 1.0, 1.2)

M. S. Bhuvaneswari, S. Selvasekarapandian, Shinobu Fujihara, Shinnosuke Koji

Research output: Contribution to journalArticle

16 Citations (Scopus)

Abstract

Lithium cobalt vanadate LixCoVO4 (x = 0.8; 1.0; 1.2) has been prepared by a solid state reaction method. The XRD analysis confirms the formation of the sample. A new peak has been observed for Li 1.0CoVO4 and for Li1.2CoVO4 indicating the formation of a new phase. The XPS analysis indicates the reduction in the oxidation of vanadium and oxygen with the addition of Li in LixCoVO4 (x = 0.8, 1.0, 1.2). The impedance analysis gives the conductivity value as 2.46 × 10- 5, 6.16 × 10 - 5, 9 × 10- 5 Ω- 1 cm - 1 for LixCoVO4 (x = 0.8; 1.0; 1.2), all at 623 K. The similarity in the bulk activation energy (Ea) and the activation enthalpy for migration of ions (Eω) indicate that the conduction in Li1.2CoVO4 has been due to hopping mechanism.

Original languageEnglish
Pages (from-to)121-127
Number of pages7
JournalSolid State Ionics
Volume177
Issue number1-2
DOIs
Publication statusPublished - 2006 Jan 16

Fingerprint

Vanadium
Vanadates
Cobalt
Solid state reactions
Lithium
structural analysis
Enthalpy
X ray photoelectron spectroscopy
Activation energy
Chemical activation
impedance
Ions
Oxygen
Oxidation
vanadates
vanadium
cobalt
lithium
enthalpy
activation

Keywords

  • AC conductivity
  • Electrode material
  • Lithium cobalt vanadate
  • XPS
  • XRD

ASJC Scopus subject areas

  • Electrochemistry
  • Physical and Theoretical Chemistry
  • Energy Engineering and Power Technology
  • Materials Chemistry
  • Condensed Matter Physics

Cite this

Structural, XPS and impedance analysis of LixCoVO4 (x = 0.8, 1.0, 1.2). / Bhuvaneswari, M. S.; Selvasekarapandian, S.; Fujihara, Shinobu; Koji, Shinnosuke.

In: Solid State Ionics, Vol. 177, No. 1-2, 16.01.2006, p. 121-127.

Research output: Contribution to journalArticle

Bhuvaneswari, M. S. ; Selvasekarapandian, S. ; Fujihara, Shinobu ; Koji, Shinnosuke. / Structural, XPS and impedance analysis of LixCoVO4 (x = 0.8, 1.0, 1.2). In: Solid State Ionics. 2006 ; Vol. 177, No. 1-2. pp. 121-127.
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