Structure analysis of highly S4-ruffled bis(2-methylimidazole)(meso-tetraethylporphyrinato)iron(III) chloride

Yoshiki Ohgo; Takahisa Ikeue; Takashi Saitoh; Mikio Nakamura

doi:10.1246/cl.2002.432

Structure analysis of highly S₄-ruffled bis(2-methylimidazole)(meso-tetraethylporphyrinato)iron(III) chloride

Yoshiki Ohgo, Takahisa Ikeue, Takashi Saitoh, Mikio Nakamura

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

The X-ray crystallographic analysis of low spin bis(2-methylimidazole)(meso-tetraethylporphyrinato)iron(III) has revealed that the porphyrin ring is highly S₄-ruffled and that the maximum deviation of the meso-carbon from the least-squares plane of the [Fe(C₂₀N₄)] core reaches as much as 0.73(1) Å.

Original language	English
Pages (from-to)	432-433
Number of pages	2
Journal	Chemistry Letters
Issue number	4
DOIs	https://doi.org/10.1246/cl.2002.432
Publication status	Published - 2002 Apr 5
Externally published	Yes

ASJC Scopus subject areas

Chemistry(all)

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title = "Structure analysis of highly S4-ruffled bis(2-methylimidazole)(meso-tetraethylporphyrinato)iron(III) chloride",

abstract = "The X-ray crystallographic analysis of low spin bis(2-methylimidazole)(meso-tetraethylporphyrinato)iron(III) has revealed that the porphyrin ring is highly S4-ruffled and that the maximum deviation of the meso-carbon from the least-squares plane of the [Fe(C20N4)] core reaches as much as 0.73(1) {\AA}.",

author = "Yoshiki Ohgo and Takahisa Ikeue and Takashi Saitoh and Mikio Nakamura",

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AU - Ohgo, Yoshiki

AU - Ikeue, Takahisa

AU - Saitoh, Takashi

AU - Nakamura, Mikio

PY - 2002/4/5

Y1 - 2002/4/5

N2 - The X-ray crystallographic analysis of low spin bis(2-methylimidazole)(meso-tetraethylporphyrinato)iron(III) has revealed that the porphyrin ring is highly S4-ruffled and that the maximum deviation of the meso-carbon from the least-squares plane of the [Fe(C20N4)] core reaches as much as 0.73(1) Å.

AB - The X-ray crystallographic analysis of low spin bis(2-methylimidazole)(meso-tetraethylporphyrinato)iron(III) has revealed that the porphyrin ring is highly S4-ruffled and that the maximum deviation of the meso-carbon from the least-squares plane of the [Fe(C20N4)] core reaches as much as 0.73(1) Å.

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DO - 10.1246/cl.2002.432

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Structure analysis of highly S₄-ruffled bis(2-methylimidazole)(meso-tetraethylporphyrinato)iron(III) chloride

Abstract

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