Structure and reactivity of bimetallic ConVm + cluster ions

Atsushi Nakajima, Takashi Kishi, Tsuneyoshi Sugioka, Yasutomo Sone, Koji Kaya

Research output: Contribution to journalArticle

27 Citations (Scopus)

Abstract

The reaction of bimetallic ConVm + cluster ions, generated by laser vaporization, toward hydrogen was investigated by using a fast-flow reactor. Compared with pure Con + cluster ions, the reactivity of Con-1V+ cluster ions exhibits a drastic decrease at n ≥ 13 similar to that of neutral ConVm clusters. The result can be explained in terms of their geometrical structure; at n ≥ 13, the V atom is located at the center of the cluster and is surrounded by Co atoms.

Original languageEnglish
Pages (from-to)6833-6835
Number of pages3
JournalJournal of Physical Chemistry
Volume95
Issue number18
Publication statusPublished - 1991

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reactivity
Ions
Atoms
ions
Vaporization
Hydrogen
Lasers
atoms
reactors
hydrogen
lasers

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry

Cite this

Nakajima, A., Kishi, T., Sugioka, T., Sone, Y., & Kaya, K. (1991). Structure and reactivity of bimetallic ConVm + cluster ions. Journal of Physical Chemistry, 95(18), 6833-6835.

Structure and reactivity of bimetallic ConVm + cluster ions. / Nakajima, Atsushi; Kishi, Takashi; Sugioka, Tsuneyoshi; Sone, Yasutomo; Kaya, Koji.

In: Journal of Physical Chemistry, Vol. 95, No. 18, 1991, p. 6833-6835.

Research output: Contribution to journalArticle

Nakajima, A, Kishi, T, Sugioka, T, Sone, Y & Kaya, K 1991, 'Structure and reactivity of bimetallic ConVm + cluster ions', Journal of Physical Chemistry, vol. 95, no. 18, pp. 6833-6835.
Nakajima, Atsushi ; Kishi, Takashi ; Sugioka, Tsuneyoshi ; Sone, Yasutomo ; Kaya, Koji. / Structure and reactivity of bimetallic ConVm + cluster ions. In: Journal of Physical Chemistry. 1991 ; Vol. 95, No. 18. pp. 6833-6835.
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