Structured spinel oxide positive electrodes of magnesium rechargeable batteries: High rate performance and high cyclability by interconnected bimodal pores and vanadium oxide coating

Kanji Ishii, Shunsuke Doi, Ryuta Ise, Toshihiko Mandai, Yuya Oaki, Shunsuke Yagi, Hiroaki Imai

Research output: Contribution to journalArticle

Abstract

A structured spinel oxide as a positive-electrode active material for magnesium rechargeable batteries was produced using a propylene-oxide-driven sol–gel method and subsequent vanadium oxide coating. Porous frameworks consisting of MgMn2O4 nanoparticles having diameters of ∼10 nm exhibited a large specific surface area of ∼150 m2 g−1 and interconnected bimodal pores distributed in the micrometer (1–10 μm) and nanometer (10–100 nm) regions. Hierarchical conduction paths constructed by mixing the porous frameworks with carbon nanoparticles reduced the overpotential for the insertion and extraction of magnesium ions and increased the redox capacity in an ionic-liquid electrolyte system. Moreover, the surface coating of vanadium oxide on the spinel oxide nanoparticles enhanced the extraction of magnesium ions and suppressed the decomposition of the electrolyte. The electrochemical properties, such as the capacities, rate capabilities, and cyclabilities, of the positive electrodes were largely improved by the structured spinel oxide frameworks.

Original languageEnglish
Article number152556
JournalJournal of Alloys and Compounds
DOIs
Publication statusAccepted/In press - 2019 Jan 1

Keywords

  • Coating
  • Mg battery
  • Morphology control
  • Polymerized complex method
  • Positive electrode

ASJC Scopus subject areas

  • Mechanics of Materials
  • Mechanical Engineering
  • Metals and Alloys
  • Materials Chemistry

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