Studies toward the synthesis of perforatumone: Synthesis of the 7-OXABICYCLO[4.2.1]NONANE-8,9-DIONE CORE

Tatsuki Nakajima, Keita Takiguchi, Keisuke Yoshida, Akihiro Ogura, Kenichi Takao

Research output: Contribution to journalArticle

Abstract

Construction of the unique bridged bicyclic skeleton, 7-oxabicyclo[4.2.1]nonane-8,9-dione, of perforatumone was achieved. Key steps included a Dieckmann-type condensation, a Claisen rearrangement, and an intramolecular Michael reaction.

Original languageEnglish
Pages (from-to)661-668
Number of pages8
JournalHeterocycles
DOIs
Publication statusPublished - 2019 Jan 1

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Skeleton
Condensation
perforatumone
nonane

ASJC Scopus subject areas

  • Analytical Chemistry
  • Pharmacology
  • Organic Chemistry

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Studies toward the synthesis of perforatumone : Synthesis of the 7-OXABICYCLO[4.2.1]NONANE-8,9-DIONE CORE. / Nakajima, Tatsuki; Takiguchi, Keita; Yoshida, Keisuke; Ogura, Akihiro; Takao, Kenichi.

In: Heterocycles, 01.01.2019, p. 661-668.

Research output: Contribution to journalArticle

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