@article{bcfbb0f87ea841fa9f24a981ee647ae2,
title = "Studies toward the total synthesis of irumamycin: stereoselective preparation of the C(15)-C(27) segment via two-directional chain synthesis",
abstract = "The basic structure of the C(15)-C(27) part of irumamycin (1) was synthesized. Stereoselective assembly of C16, 17, 22, and an extra C21 stereocenter was achieved by two-directional Brown's asymmetric allyl boration. Group selective PMP acetal formation and oxidative cleavage of vinyl group facilitated the differentiation of the ends of a two-directionally synthesized chain.",
author = "Tomoyasu Hirose and Toshiaki Sunazuka and Daisuke Yamamoto and Mutsumi Mouri and Yoshiaki Hagiwara and Takanori Matsumaru and Eisuke Kaji and Satoshi Omura",
note = "Funding Information: This work was supported by a Grant from the 21st Century COE Program, Ministry of Education, Culture, Sports, Science and Technology, and the Kato Memorial Bioscience Foundation. We also thank Ms. A. Nakagawa, Ms. C. Sakabe, Ms. N. Sato, and Ms. Y. Kawauchi for the various instrumental analyses.",
year = "2007",
month = jan,
day = "15",
doi = "10.1016/j.tetlet.2006.11.079",
language = "English",
volume = "48",
pages = "413--416",
journal = "Tetrahedron Letters",
issn = "0040-4039",
publisher = "Elsevier Limited",
number = "3",
}