(+) 589-Λ-Amminebromobis(ethylenediamine-N,N′)cobalt(III) dibromide

Hiroo Nakagawa; Shigeru Ohba; Kouichi Asakura; Tomohito Miura; Akiko Tanaka; Shuichi Osanai

doi:10.1107/S0108270196013479

(+) ₅₈₉-Λ-Amminebromobis(ethylenediamine-N,N′)cobalt(III) dibromide

Hiroo Nakagawa, Shigeru Ohba, Kouichi Asakura, Tomohito Miura, Akiko Tanaka, Shuichi Osanai

Research output: Contribution to journal › Article › peer-review

9 Citations (Scopus)

Abstract

The absolute configuration of (+)₅₈₉-cis-[CoBr(C₂H₈-N₂) ₂(NH₃)]²⁺ was confirmed to be Λ. The ethylenediamine five-membered chelate rings take the lel₂ conformation. There are N-H⋯Br intermolecular hydrogen bonds with N⋯Br distances ranging from 3.267 (9) to 3.715 (8) Å.

Original language	English
Pages (from-to)	216-217
Number of pages	2
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	53
Issue number	2
DOIs	https://doi.org/10.1107/S0108270196013479
Publication status	Published - 1997 Feb 15

ASJC Scopus subject areas

Biochemistry, Genetics and Molecular Biology(all)

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title = "(+) 589-Λ-Amminebromobis(ethylenediamine-N,N′)cobalt(III) dibromide",

abstract = "The absolute configuration of (+)589-cis-[CoBr(C2H8-N2) 2(NH3)]2+ was confirmed to be Λ. The ethylenediamine five-membered chelate rings take the lel2 conformation. There are N-H⋯Br intermolecular hydrogen bonds with N⋯Br distances ranging from 3.267 (9) to 3.715 (8) {\AA}.",

author = "Hiroo Nakagawa and Shigeru Ohba and Kouichi Asakura and Tomohito Miura and Akiko Tanaka and Shuichi Osanai",

year = "1997",

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language = "English",

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T1 - (+) 589-Λ-Amminebromobis(ethylenediamine-N,N′)cobalt(III) dibromide

AU - Nakagawa, Hiroo

AU - Ohba, Shigeru

AU - Asakura, Kouichi

AU - Miura, Tomohito

AU - Tanaka, Akiko

AU - Osanai, Shuichi

PY - 1997/2/15

Y1 - 1997/2/15

N2 - The absolute configuration of (+)589-cis-[CoBr(C2H8-N2) 2(NH3)]2+ was confirmed to be Λ. The ethylenediamine five-membered chelate rings take the lel2 conformation. There are N-H⋯Br intermolecular hydrogen bonds with N⋯Br distances ranging from 3.267 (9) to 3.715 (8) Å.

AB - The absolute configuration of (+)589-cis-[CoBr(C2H8-N2) 2(NH3)]2+ was confirmed to be Λ. The ethylenediamine five-membered chelate rings take the lel2 conformation. There are N-H⋯Br intermolecular hydrogen bonds with N⋯Br distances ranging from 3.267 (9) to 3.715 (8) Å.

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DO - 10.1107/S0108270196013479

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JO - Acta Crystallographica Section C: Crystal Structure Communications

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IS - 2

ER -

(+) ₅₈₉-Λ-Amminebromobis(ethylenediamine-N,N′)cobalt(III) dibromide

Abstract

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