Sulphate ester of trans-4-hydroxypipecolic acid in seeds of Peltophorum

Stephen V. Evans, Tony K.M. Shing, Robin T. Aplin, Linda E. Fellows, George W.J. Fleet

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Abstract

An acidic compound isolated from seed of the legume Peltophorum africanum has been characterised on the basis of FAB-MS, EIMS, 13C and 1H NMR as trans-4-hydroxypipecolic acid-4-sulphate. This is the first naturally occurring sulphate ester of a non-protein amino acid to be described. The possible systematic significance of the distribution of the ester within Peltophorum and related genera is considered.

Original languageEnglish
Pages (from-to)2593-2596
Number of pages4
JournalPhytochemistry
Volume24
Issue number11
DOIs
Publication statusPublished - 1985 Oct 29

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Keywords

  • C NMR
  • EIMS
  • FAB-MS
  • H NMR
  • Leguminosae
  • Peltophorum africanum
  • chemotaxonomy.
  • non-protein amino acid
  • sulphate ester
  • trans-4-hydroxypipecolic acid-4-sulphate

ASJC Scopus subject areas

  • Biochemistry
  • Molecular Biology
  • Plant Science
  • Horticulture

Cite this

Evans, S. V., Shing, T. K. M., Aplin, R. T., Fellows, L. E., & Fleet, G. W. J. (1985). Sulphate ester of trans-4-hydroxypipecolic acid in seeds of Peltophorum. Phytochemistry, 24(11), 2593-2596. https://doi.org/10.1016/S0031-9422(00)80675-5