Superconducting properties of a mixed anion layered compound, Ca and F co-doped LaFeAsO with T c = 31.5 K

Kodai Kaneyasu, Ryosuke Sakagami, Masanori Matoba, Yoichi Kamihara

Research output: Contribution to journalArticle

Abstract

Polycrystalline Ca and F co-doped LaFeAsO samples (La 1-x Ca x FeAsO 1-y F y ) were synthesized by solid-state reactions. Samples with nominal composition: (y - x) ≤ 0.05 did not show superconductivity at temperatures T > 4.2 K, although an anomalous kink of the ρ-T curves, which is related to crystallographic phase transitions, was observed at T ∼ 150 K. Samples with nominal composition: (y - x) ≥ 0.15 did exhibit superconductivity. The superconducting transition temperature (T c ) of co-doped LaFeAsO with nominal composition: (x, y) = (0.25, 0.50) was determined to be T c = 31.5 K, which is higher than the highest T c value observed for LaFeAsO 1-x F x materials synthesized under ambient pressure.

Original languageEnglish
Article number030911
JournalJapanese journal of applied physics
Volume58
Issue number3
DOIs
Publication statusPublished - 2019 Mar 1

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Negative ions
anions
Superconductivity
superconductivity
Chemical analysis
Solid state reactions
Superconducting transition temperature
Phase transitions
transition temperature
solid state
curves
Temperature
temperature

ASJC Scopus subject areas

  • Engineering(all)
  • Physics and Astronomy(all)

Cite this

Superconducting properties of a mixed anion layered compound, Ca and F co-doped LaFeAsO with T c = 31.5 K . / Kaneyasu, Kodai; Sakagami, Ryosuke; Matoba, Masanori; Kamihara, Yoichi.

In: Japanese journal of applied physics, Vol. 58, No. 3, 030911, 01.03.2019.

Research output: Contribution to journalArticle

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