Syntheses of RuHCl(CO)(PAr3)3 and RuH2(CO)(PAr3)3 Containing various triarylphosphines and their use for arylation of sterically congested aromatic C-H bonds

Yohei Ogiwara, Masashi Miyake, Takuya Kochi, Fumitoshi Kakiuchi

Research output: Contribution to journalArticle

12 Citations (Scopus)

Abstract

A series of ruthenium complexes, RuHCl(CO)(PAr3)3 and RuH2(CO)(PAr3)3, containing various triarylphosphines were synthesized. Screening of these complexes as catalysts for direct arylation of sterically congested ortho C-H bonds of aromatic ketones improved the yields of the arylation products.

Original languageEnglish
Pages (from-to)159-164
Number of pages6
JournalOrganometallics
Volume36
Issue number1
DOIs
Publication statusPublished - 2017 Jan 1

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Carbon Monoxide
ketones
ruthenium
screening
catalysts
Ruthenium
synthesis
products
Ketones
Screening
Catalysts

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

Cite this

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abstract = "A series of ruthenium complexes, RuHCl(CO)(PAr3)3 and RuH2(CO)(PAr3)3, containing various triarylphosphines were synthesized. Screening of these complexes as catalysts for direct arylation of sterically congested ortho C-H bonds of aromatic ketones improved the yields of the arylation products.",
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AU - Miyake, Masashi

AU - Kochi, Takuya

AU - Kakiuchi, Fumitoshi

PY - 2017/1/1

Y1 - 2017/1/1

N2 - A series of ruthenium complexes, RuHCl(CO)(PAr3)3 and RuH2(CO)(PAr3)3, containing various triarylphosphines were synthesized. Screening of these complexes as catalysts for direct arylation of sterically congested ortho C-H bonds of aromatic ketones improved the yields of the arylation products.

AB - A series of ruthenium complexes, RuHCl(CO)(PAr3)3 and RuH2(CO)(PAr3)3, containing various triarylphosphines were synthesized. Screening of these complexes as catalysts for direct arylation of sterically congested ortho C-H bonds of aromatic ketones improved the yields of the arylation products.

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