Syntheses of RuHCl(CO)(PAr3)3 and RuH2(CO)(PAr3)3 Containing various triarylphosphines and their use for arylation of sterically congested aromatic C-H bonds

Yohei Ogiwara, Masashi Miyake, Takuya Kochi, Fumitoshi Kakiuchi

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Abstract

A series of ruthenium complexes, RuHCl(CO)(PAr3)3 and RuH2(CO)(PAr3)3, containing various triarylphosphines were synthesized. Screening of these complexes as catalysts for direct arylation of sterically congested ortho C-H bonds of aromatic ketones improved the yields of the arylation products.

Original languageEnglish
Pages (from-to)159-164
Number of pages6
JournalOrganometallics
Volume36
Issue number1
DOIs
Publication statusPublished - 2017 Jan 1

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ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

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