TY - JOUR
T1 - Synthesis and absolute configuration of the naturally occurring cyano glucoside simmondsin
AU - Chida, Noritaka
AU - Yamada, Ken
AU - Ogawa, Seiichiro
PY - 1992
Y1 - 1992
N2 - The synthesis of the naturally occurring cyano glucoside simmondsin, 1, is reported. An optically active cyclitol, L-quebrachitol 2, was stereoselectively converted into the aglycone 19, which was condensed with D-glucose, followed by deprotection to provide simmondsin 1. This synthesis successfully determined the absolute configuration of the natural product.
AB - The synthesis of the naturally occurring cyano glucoside simmondsin, 1, is reported. An optically active cyclitol, L-quebrachitol 2, was stereoselectively converted into the aglycone 19, which was condensed with D-glucose, followed by deprotection to provide simmondsin 1. This synthesis successfully determined the absolute configuration of the natural product.
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U2 - 10.1039/p19920001131
DO - 10.1039/p19920001131
M3 - Article
AN - SCOPUS:37049083845
SN - 1472-7781
SP - 1131
EP - 1137
JO - Journal of the Chemical Society. Perkin Transactions 1
JF - Journal of the Chemical Society. Perkin Transactions 1
IS - 9
ER -