Synthesis and character of new bis(isoxazoline) ligands

Toshio Shinohara, Kazuhiko Wakita, Midori A. Arai, Takayoshi Arai, Hiroaki Sasai

Research output: Contribution to journalArticle

11 Citations (Scopus)

Abstract

Synthesis of two kinds of new bis(isoxazoline) ligand, achiral 2,2'bis(isoxazolinyl)propane and (R)-2,2'-bis(isoxazolinyl)-1,1'-binaphthyl bearing an axial chirality is described. Both of the bis(isoxazoline) ligands accelerated the Pd(II)-catalyzed Wacker-type cyclization of alkenyl alcohol. The isoxazoline ligands were found to be essential to promote the cyclization.

Original languageEnglish
Pages (from-to)587-593
Number of pages7
JournalHeterocycles
Volume59
Issue number2
DOIs
Publication statusPublished - 2003 Mar 1

ASJC Scopus subject areas

  • Analytical Chemistry
  • Pharmacology
  • Organic Chemistry

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  • Cite this

    Shinohara, T., Wakita, K., Arai, M. A., Arai, T., & Sasai, H. (2003). Synthesis and character of new bis(isoxazoline) ligands. Heterocycles, 59(2), 587-593. https://doi.org/10.3987/com-02-s57