Synthesis and characterization of single-phase TlSr2Ca2Cu3Oy

S. Adachi, T. Shibata, T. Tatsuki, T. Tamura, K. Tanabe, Shinobu Fujihara, T. Kimura

Research output: Contribution to journalArticle

7 Citations (Scopus)

Abstract

We successfully prepared a single-phase sample of TlSr2Ca2Cu3Oy by high pressure synthesis. The powder mixture with a nominal composition of TlSr2Ca2Cu3O9.4 was heat-treated at 1100 °C for 4 h under 6 GPa. Powder X-ray diffraction revealed that the obtained sample was single-phase of the 1223 structure with a tetragonal unit cell (a = 3.813(4) angstroms, c = 15.24(1) angstroms. The sample exhibited Meissner signals below 86 K. The resistivity linearly decreased with decreasing temperature above 86 K and the thermoelectric power at 290 K was found to be nearly zero. These results imply that the hole concentration of the sample is nearly optimized. The sample showed an excellent dependence of the irreversibility field Birr on reduced temperature (1-T/Tc), which is comparable to that for (Cu,C)-1223.

Original languageEnglish
Pages (from-to)15-20
Number of pages6
JournalPhysica C: Superconductivity and its Applications
Volume324
Issue number1
DOIs
Publication statusPublished - 1999 Oct 15

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Hole concentration
Thermoelectric power
synthesis
Powders
X ray powder diffraction
Temperature
Chemical analysis
heat
electrical resistivity
temperature
cells
diffraction
x rays
Hot Temperature

ASJC Scopus subject areas

  • Condensed Matter Physics

Cite this

Synthesis and characterization of single-phase TlSr2Ca2Cu3Oy. / Adachi, S.; Shibata, T.; Tatsuki, T.; Tamura, T.; Tanabe, K.; Fujihara, Shinobu; Kimura, T.

In: Physica C: Superconductivity and its Applications, Vol. 324, No. 1, 15.10.1999, p. 15-20.

Research output: Contribution to journalArticle

Adachi, S. ; Shibata, T. ; Tatsuki, T. ; Tamura, T. ; Tanabe, K. ; Fujihara, Shinobu ; Kimura, T. / Synthesis and characterization of single-phase TlSr2Ca2Cu3Oy. In: Physica C: Superconductivity and its Applications. 1999 ; Vol. 324, No. 1. pp. 15-20.
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