Synthesis and crystal structure of polymeric oxovanadium(V) complexes with tetradentate Schiff base ligands

Masanobu Tsuchimoto; Eriko Yasuda; Shigeru Ohba

doi:10.1246/cl.2000.562

Synthesis and crystal structure of polymeric oxovanadium(V) complexes with tetradentate Schiff base ligands

Masanobu Tsuchimoto, Eriko Yasuda, Shigeru Ohba

Department of Humanities and Social Sciences

Research output: Contribution to journal › Article

15 Citations (Scopus)

Abstract

New polymeric oxovanadium(V) complexes with tetradentate Schiff base ligands, [VO(Xsalen)]SbF₆(H₂Xsalen: N,N′-di-Xsalicylidene-1,2-ethanediamine; X=5-MeO (methoxy) and H ) were prepared from monomeric [VO(XSalen)(H₂O)]NO₃•H₂O by changing the counter anion. X-Ray crystal structure analysis of [VO(5-MeOsalen)]SbF₆ showed that the complex has ⋯V^v=O⋯V^v=O⋯ chains in the crystals.

Original language	English
Pages (from-to)	562-563
Number of pages	2
Journal	Chemistry Letters
Issue number	5
DOIs	https://doi.org/10.1246/cl.2000.562
Publication status	Published - 2000 Jan 1

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Chemistry(all)

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Tsuchimoto, M., Yasuda, E., & Ohba, S. (2000). Synthesis and crystal structure of polymeric oxovanadium(V) complexes with tetradentate Schiff base ligands. Chemistry Letters, (5), 562-563. https://doi.org/10.1246/cl.2000.562

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abstract = "New polymeric oxovanadium(V) complexes with tetradentate Schiff base ligands, [VO(Xsalen)]SbF6(H2Xsalen: N,N′-di-Xsalicylidene-1,2-ethanediamine; X=5-MeO (methoxy) and H ) were prepared from monomeric [VO(XSalen)(H2O)]NO3•H2O by changing the counter anion. X-Ray crystal structure analysis of [VO(5-MeOsalen)]SbF6 showed that the complex has ⋯Vv=O⋯Vv=O⋯ chains in the crystals.",

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10.1246/cl.2000.562