Synthesis and crystal structures of polymeric nitridomanganese(V) and nitridochromium(V) complexes with a tetradentate schiff base ligand

Masanobu Tsuchimoto, Hirofumi Iwamoto, Masaaki Kojima, Shigeru Ohba

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

Novel polymeric nitridomanganese(V) and nitridochromium(V) complexes with a Schiff base ligand, [MnN(salpn)] and [CrN(salpn)] (H2(salpn): N,N'-disalicylidene-1,3-propanediamine) were prepared by photolysis of azido complexes. X-ray crystal structure analyses show that the complexes have an isostructual polymeric structure (⋯M≡N⋯M≡N⋯) with the N⋯M distances being 2.528(3) Å for M=Mn, and 2.508(2) Å for M=Cr.

Original languageEnglish
Pages (from-to)33-38
Number of pages6
JournalMolecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals
Volume376
DOIs
Publication statusPublished - 2002

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Schiff Bases
Photolysis
imines
photolysis
Crystal structure
Ligands
X rays
ligands
crystal structure
synthesis
x rays
trimethylenediamine
oligomycin sensitivity-conferring protein

Keywords

  • Nitridochromium(V) complex
  • Nitridomanganese(V) complex
  • Polymeric structure

ASJC Scopus subject areas

  • Condensed Matter Physics

Cite this

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abstract = "Novel polymeric nitridomanganese(V) and nitridochromium(V) complexes with a Schiff base ligand, [MnN(salpn)] and [CrN(salpn)] (H2(salpn): N,N'-disalicylidene-1,3-propanediamine) were prepared by photolysis of azido complexes. X-ray crystal structure analyses show that the complexes have an isostructual polymeric structure (⋯M≡N⋯M≡N⋯) with the N⋯M distances being 2.528(3) {\AA} for M=Mn, and 2.508(2) {\AA} for M=Cr.",
keywords = "Nitridochromium(V) complex, Nitridomanganese(V) complex, Polymeric structure",
author = "Masanobu Tsuchimoto and Hirofumi Iwamoto and Masaaki Kojima and Shigeru Ohba",
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language = "English",
volume = "376",
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T1 - Synthesis and crystal structures of polymeric nitridomanganese(V) and nitridochromium(V) complexes with a tetradentate schiff base ligand

AU - Tsuchimoto, Masanobu

AU - Iwamoto, Hirofumi

AU - Kojima, Masaaki

AU - Ohba, Shigeru

PY - 2002

Y1 - 2002

N2 - Novel polymeric nitridomanganese(V) and nitridochromium(V) complexes with a Schiff base ligand, [MnN(salpn)] and [CrN(salpn)] (H2(salpn): N,N'-disalicylidene-1,3-propanediamine) were prepared by photolysis of azido complexes. X-ray crystal structure analyses show that the complexes have an isostructual polymeric structure (⋯M≡N⋯M≡N⋯) with the N⋯M distances being 2.528(3) Å for M=Mn, and 2.508(2) Å for M=Cr.

AB - Novel polymeric nitridomanganese(V) and nitridochromium(V) complexes with a Schiff base ligand, [MnN(salpn)] and [CrN(salpn)] (H2(salpn): N,N'-disalicylidene-1,3-propanediamine) were prepared by photolysis of azido complexes. X-ray crystal structure analyses show that the complexes have an isostructual polymeric structure (⋯M≡N⋯M≡N⋯) with the N⋯M distances being 2.528(3) Å for M=Mn, and 2.508(2) Å for M=Cr.

KW - Nitridochromium(V) complex

KW - Nitridomanganese(V) complex

KW - Polymeric structure

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