Synthesis and crystal structures of polymeric nitridomanganese(V) and nitridochromium(V) complexes with a tetradentate schiff base ligand

Masanobu Tsuchimoto, Hirofumi Iwamoto, Masaaki Kojima, Shigeru Ohba

Research output: Contribution to journalConference article

1 Citation (Scopus)

Abstract

Novel polymeric nitridomanganese(V) and nitridochromium(V) complexes with a Schiff base ligand, [MnN(salpn)] and [CrN(salpn)] (H2(salpn): N,N'-disalicylidene-1,3-propanediamine) were prepared by photolysis of azido complexes. X-ray crystal structure analyses show that the complexes have an isostructual polymeric structure (⋯M≡N⋯M≡N⋯) with the N⋯M distances being 2.528(3) Å for M=Mn, and 2.508(2) Å for M=Cr.

Original languageEnglish
Pages (from-to)33-38
Number of pages6
JournalMolecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals
Volume376
DOIs
Publication statusPublished - 2002 Dec 1
EventProceedings of the Interdisciplinary Symposium on Multifunctionality of Inorganic , Organic, and Their Hybrid Solids - Honolulu, HI, United States
Duration: 2000 Dec 152000 Dec 18

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Keywords

  • Nitridochromium(V) complex
  • Nitridomanganese(V) complex
  • Polymeric structure

ASJC Scopus subject areas

  • Condensed Matter Physics

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