Synthesis and properties of the 3-tert-butyl-7-trifluoromethyl-1,4-dihydro-1-phenyl-1,2,4-benzotriazin-4-yl radical

Yusuke Takahashi, Youhei Miura, Naoki Yoshioka

Research output: Contribution to journalArticle

17 Citations (Scopus)

Abstract

A novel benzotriazinyl radical, 3-tert-butyl-7-trifluoromethyl-1,4-dihydro-1-phenyl-1,2,4-benzotriazin-4-yl (2), was prepared and its magneto-structural correlation was investigated. An X-ray crystallographic analysis revealed that 2 forms a 1D column assembly, however, π-π interaction was not the driving force of the column structure. The magnetic susceptibility obeyed the Curie-Weiss law with C = 0.369 emu K mol<sup>-1</sup> and = +0.7 K. The thermal behavior of χ<inf>m</inf>T was described using the 1D ferromagnetic chain model with J/k<inf>B</inf> = +0.91 K.

Original languageEnglish
Pages (from-to)4783-4789
Number of pages7
JournalNew Journal of Chemistry
Volume39
Issue number6
DOIs
Publication statusPublished - 2015 Jun 1

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Magnetic susceptibility
X rays
Hot Temperature

ASJC Scopus subject areas

  • Chemistry(all)
  • Catalysis
  • Materials Chemistry

Cite this

Synthesis and properties of the 3-tert-butyl-7-trifluoromethyl-1,4-dihydro-1-phenyl-1,2,4-benzotriazin-4-yl radical. / Takahashi, Yusuke; Miura, Youhei; Yoshioka, Naoki.

In: New Journal of Chemistry, Vol. 39, No. 6, 01.06.2015, p. 4783-4789.

Research output: Contribution to journalArticle

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